Microwave Chemistry-Synthesis of Phenytoin  Why does the DEPT 135 spectrum only show three peaks while the full       13C{1H}-NMR spectrum displays seven peaks?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Microwave Chemistry-Synthesis of Phenytoin

 Why does the DEPT 135 spectrum only show three peaks while the full       13C{1H}-NMR spectrum displays seven peaks?

 

two tall and one medium
signal in the middle
220
200
180
160
140
120
100
80
60
40
20
DEPT 135
two tall and one medium
signal in the middle
220
60
20
200
180
160
140
120
100
80
40
-175.217
- 156.416
139.961
-129.240
128.847
128.590
128.385
127.230
127.177
126.956
-7.644
s 40.374
40.165
39.747
39.538
39.121
Transcribed Image Text:two tall and one medium signal in the middle 220 200 180 160 140 120 100 80 60 40 20 DEPT 135 two tall and one medium signal in the middle 220 60 20 200 180 160 140 120 100 80 40 -175.217 - 156.416 139.961 -129.240 128.847 128.590 128.385 127.230 127.177 126.956 -7.644 s 40.374 40.165 39.747 39.538 39.121
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