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- Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.Which pair of structures are enantiomers? COOH CH3 H HO HOOC OH CH3 H CH2CH3 Br H CH2CH3 Br cl H CH2CH3 CH3 H CH3 HO HO H CH2CH3 II, III I, II, III |, ||| I, II4) What pairs of compounds I-IV below are enantiomers to each me buy that takan B../.4- C other? CL I CL I II A CL II CL III II B NEL CLASZOK I IV III CI None D تكرة IV All E
- h) i) + CH3CHSSCHCH3 CH3 CH3 Cl₂ [H] FeCl3 ? ?8) Identify enantiomers. C E A CI H ICL F CI H Cle H. CI H. CI H CI CI H. F H. 'F 'F H. F H H. F H H H. A) B and D, A and C B) B and D C) A and B, A and D, B and C, C and D D) B and D, A and B, A and D, B and C, C and D E) A and CWhich compounds contain stereocenters? CH3 -CH-CH3 о OH OH -CH-CH2 || CH3 OH CH-CH-CH3 CH3 C-CH2-CH3 CH3 IV III, IV I, II I, ||| II, IV
- 1E.) Which of the following two conformers is lower in energy? Both conformers are of equal enery O A Conformer A is lower in energy. B Conformer B is lower in energy. It cannot be determinedAre the pairs molecules given below (pair a, b, c) related to each other as constitutional isomers, enantiomers, diastereomers, or identical? a Relationships OH Et Et Но- -H- H. .CH3 a: CI CH3 HO `H b: CI H CI c: a Relationships H H. CI-CH2CH3 H H H3CH2C- CI H3CH2C- H -CI a: b: H- -CI -- ČH2CH3 CI C: a Relationships and a: .CI b: c:Classify each compound as identical to A or its enantiomer. CHO CHO H OH CHO a. CH,CH-C--OH CumCH,CH3 H OH b. d. HO C. ČH,CH3 н он CH;CH CHO CHO A
- a) Draw the two ring flipped conformers of each molecule A and B. Indicate the more stable conformer, respectively. CH3 fCH3 H,C. CH3 H3C. CH3 CI CI A B a) Which is more stable between A and B? Why?Which stereoisomer has the lower overall energy? Draw the chair for the lowest energy conformation.2. H3CO H3CO HO 1. Consider the molecule shown below. [1] Draw the two chair conformations for the compound. [2] Identify which of the two chair conformations is more stable and explain why. H3CO Jonoto NH₂ How are the following molecules related? (exactly the same, completely different, constitutional isomers, enantiomers, or diastereomers). OH OH OCH3 HO“ OH H3CO H3CO is content is protected and may not be shared, uploaded of ributed OCH3 HO,,, OH O... "OCH3