Match the following aqueous solutions with the appropriate letter from the column on the right. 1.9.00x 102 m Al(NO3)3 2.0.130 m K₂S 3.0.210 m 4.0.450 m Glucose (nonelectrolyte) CoSO4 A. Highest boiling point B. Second highest boiling point C.Third highest boiling point D. Lowest boiling point

Match the following aqueous solutions with the appropriate letter from the column on the right. 1.9.00x 102 m Al(NO3)3 2.0.130 m K₂S 3.0.210 m 4.0.450 m Glucose (nonelectrolyte) CoSO4 A. Highest boiling point B. Second highest boiling point C.Third highest boiling point D. Lowest boiling point

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter13: Solutions And Their Behavior

Section: Chapter Questions

Problem 64GQ: The solubility of NaCl in water at 100 C is 39.1 g/100. g of water Calculate the boiling point of...

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A forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?
1. Vapor pressure: Arrange the following aqueous solutions in order of increasing vapor pressure at 25°C: 0.35 m C2H4(OH)2 (ethylene glycol, nonvolatile solute); 0.50 m sugar; 0.20 m KBr; and 0.20 m Na2SO4. C2H4(OH)2 < sugar < KBr < Na2SO4 Na2SO4 < sugar < KBr < C2H4(OH)2 sugar < C2H4(OH)2 < KBr < Na2SO4 KBr < sugar < Na2SO4 < C2H4(OH)2
Consider two hypothetical pure substances, AB(s) and XY(s). When equal molar amounts of these substances are placed in separate 500-mL samples of water, they undergo the following reactions: AB(s)A+(aq)+B(aq)XY(s)XY(aq) a Which solution would you expect to have the lower boiling point? Why? b Would you expect the vapor pressures of the two solutions to be equal? If not, which one would you expect to have the higher vapor pressure? c Describe a procedure that would make the two solutions have the same boiling point. d If you took 250 mL of the AB(aq) solution prepared above, would it have the same boiling point as the original solution? Be sure to explain your answer. e The container of XY(aq) is left out on the bench top for several days, which allows some of the water to evaporate from the solution. How would the melting point of this solution compare to the melting point of the original solution?
When KNO3 is dissolved in water, the resulting solution is significantly colder than the water was originally. (a) Is the dissolution of KNO3 an endothermic or an exothermic process? (b) What conclusions can you draw about the intermolecular attractions involved in the process? (c) Is the resulting solution an ideal solution?
Carbon tetrachloride (CCl4) boils at 76.8C and has a density of 1.59 g/mL. (a) A solution prepared by dissolving 0.287 mol of a nonelectrolyte in 255 mL of CCl4 boils at 80.3C. What is the boiling point constant (kb) for CCl4? (b) Another solution is prepared by dissolving 37.1 g of an electrolyte (MM=167g/mol) in 244 mL of CCl4. The resulting solution boils at 85.2C. What is i for the electrolyte?
Which of the following will have the lowest total vapor pressure at 25C? a. pure water (vapor pressure = 23.8 torr at 25C) b. a solution of glucose in water with C6H12O6=0.01 c. a solution of sodium chloride in water with NaCl = 0.01 d. a solution of methanol in water with CH3OH=0.2 (Consider the vapor pressure of both methanol [143 torr at 25C] and water.)
Two samples of sodium chloride solutions are brought to a boil on a stove. One of the solutions boils at 100.10C and the other at 100.15C. a Which of the solutions is more concentrated? b Which of the solutions would have a lower freezing point? c If you split the solution that boils at 100.1C into two portions, how would the boiling points of the samples compare? Which of the following statements do you agree with regarding the determination of your answer for part c? I. The question cannot be answered with certainty without knowing the volumes of each portion. II. Making the necessary assumption that the two samples have equal volumes, I was able to correctly answer the question. III. The volumes that the sample was split into are irrelevant when determining the correct answer.
An aqueous solution containing 10.0 g of starch per liter has an osmotic pressure of 3.8 mm Hg at 25 C. (a) What is the average molar mass of starch? (The result is an average because not all starch molecules are identical.) (b) What is the freezing point of the solution? Would it be easy to determine the molecular weight of starch by measuring the freezing point depression? (Assume that the molarity and molality are the same for this solution.)
In some regions of the southwest United States, the water is very hard. For example, in Las Cruces, New Mexico, the tap water contains about 560 g of dissolved solids per milliliter. Reverse osmosis units are marketed in this area to soften water. A typical unit exerts a pressure of 8.0 atm and can produce 45 L water per day. a. Assuming all of the dissolved solids are MgCO3 and assuming a temperature of 27C, what total volume of water must be processed to produce 45 L pure water? b. Would the same system work for purifying seawater? (Assume seawater is 0.60 M NaCl.)
Benzyl acetate is one of the active components of oil of jasmine. If 0.125 g of the compound is added to 25.0 g of chloroform (CHCl3), the boiling point of the solution is 61.82 C. What is the molar mass of benzyl acetate?

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