1.8.with pi bonding.Draw a fully labelled molecular orbital diagram of the complex [Mn(CN)6]³-[15](i)What is the total number of molecular orbitals for the complex ion.(ii)If CN is replaced with Br, would you expect Ao to increase or decrease,briefly explain your answer.[1][3]

Step 1: Step 2: Step 3: Step 4:

Answered: 1.8. with pi bonding. Draw a fully…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Answer last 3 parts E to G
Among the complex ions formed by M³* (M is a transition metal in 3d block) are the following: [M(H20).J³*, [M(NH;)6]³*, and [MF6]*. These ions have the following 9 observed colors (listed in arbitrary order): yellow-orange, green, and blue. Match each complex with its color. Explain.
2D.) Draw the structure of: [Fe(Cp)(CO)(PPhs)(H)]. It is tetrahedral...use wedges and dashes as needed. Account for the electrons in the complex. Is it a 16 e or 18 e complex (Circle one). Give oxidation state of Fe: + 2EChallenge!) Since the complex here is tetrahedral, i.e., it has four different groups on it, see if you can figure out how to assign the stereochemistry, R or S, to your drawing. My drawing is: R or S (Circle one)
Write out structure representations for all isomers of the following complexes: (c) Pd(en)(SCN)2 (include linkage isomers)
4. For each of the following transition metal complex ions (a) [FeBr2(OH)(NO3)]¹- (b) [RhF3(SCN)3]4- (c) [TiBr4]³- (i) Draw the structure of the transition metal complex ion. Show the charge on the complex in your structure. Give the oxidation state of the metal. State whether the complex is high spin or low spin or not applicable. Provide reasons for your answer. (iv) Draw the arrangement of d-electrons in the ground state. Label the orbital sets. (v) Calculate the LFSE (in units of Ao or AT) for each complex. (ii) (iii)
Note the complexes: i) [Co(en)3]3+; ii.) [RuBr4(en)]-; iii.) [RuClF(en)2]+ Which of the complexes above have geometrical isomers? Show the geometrical isomers for the applicable complex(es). Which of the complexes above can have optical isomers? For each complex, explain why or why not.
[3] (ii) Explain why the 3d,2 and 3d,, orbitals of a transition metal complex in an octahedral ligand environment will no longer be degenerate according to Crystal Field Theory. Which orbital is higher in energy. Include a sketch to aid in any explanation.
oving to another question will save this response. complex [Co(NH3)6l absorbs light at a wavelength of 465 nm. What is the ligand field aplitting energy for the cormplez in Jlaole? 275 x 10 to negative x AMoving to another question will save this response.
????
Three complex ions of cobalt(III), [Co(CN),]?-, [Co(NH;),]*, and (CoF, absorb light at wavelengths of (in no particular order) 290 nm, 440 nm, and 770 nm. Match each complex ion to the appropriate wavelength absorbed. What color would you expect each solution to be?
How manyd electrons are in each metal of the following complexes? Give the oxidation number of the metal ion in each complex. 7. [Fe(NH,),J* [Cr(CO),j* [Ni(CN),J" [Fe(ox),] "ox" represents the oxalate anion with charge, -2.

Recommended textbooks for you

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry

ISBN:

9781259911156

Author:

Raymond Chang Dr., Jason Overby Professor

Publisher:

McGraw-Hill Education

Principles of Instrumental Analysis

Chemistry

ISBN:

9781305577213

Author:

Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry

ISBN:

9781259911156

Author:

Raymond Chang Dr., Jason Overby Professor

Publisher:

McGraw-Hill Education

Principles of Instrumental Analysis

Chemistry

ISBN:

9781305577213

Author:

Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:

Cengage Learning

Organic Chemistry

Chemistry

ISBN:

9780078021558

Author:

Janice Gorzynski Smith Dr.

Publisher:

McGraw-Hill Education

Chemistry: Principles and Reactions

Chemistry

ISBN:

9781305079373

Author:

William L. Masterton, Cecile N. Hurley

Publisher:

Cengage Learning

Elementary Principles of Chemical Processes, Bind…

Chemistry

ISBN:

9781118431221

Author:

Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard

Publisher:

WILEY

SEE MORE TEXTBOOKS

1.8. with pi bonding. Draw a fully labelled molecular orbital diagram of the complex [Mn(CN)6]³- [15] (i) What is the total number of molecular orbitals for the complex ion. (ii) If CN is replaced with Br, would you expect Ao to increase or decrease, briefly explain your answer. [1] [3]