Mass spectral analysis of 1-cyclohexylpropan-2-one results in several fragmentation pathways. Complete the mechanism, and give the major products for the McLafferty rearrangement pathway. Include all nonbonding electrons and charges. H₂ H₂C H₂C. CH .H :0: CH3 -e radical cationic intermediate A McLafferty Rearrangement McLafferty Products Ring structures tool Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally delete a vital part of the structure, use the undo
Mass spectral analysis of 1-cyclohexylpropan-2-one results in several fragmentation pathways. Complete the mechanism, and give the major products for the McLafferty rearrangement pathway. Include all nonbonding electrons and charges. H₂ H₂C H₂C. CH .H :0: CH3 -e radical cationic intermediate A McLafferty Rearrangement McLafferty Products Ring structures tool Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally delete a vital part of the structure, use the undo
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Mass spectral analysis of 1-cyclohexylpropan-2-one results in several fragmentation pathways. Complete the mechanism, and
give the major products for the McLafferty rearrangement pathway. Include all nonbonding electrons and charges.
H₂
C.
H
H₂C
H
H₂C.
CH
H₂
:O:
CH3
-e-
radical cationic
intermediate A
McLafferty
Rearrangement
McLafferty
Products
H₂
Ring structures tool
Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally delete a vital part of the structure, use the undo
button on the lower left of the drawing canvas.

Transcribed Image Text:Add electrons and the charge for the resulting radical
cationic intermediate, and add curved arrows for the
McLafferty rearrangement mechanism.
Select Draw Templates More
H₂C
|
H₂C
III с H
H₂
C
H₂
CH
CH3
Erase
Draw the McLafferty rearrangement products (one
radical cation and one neutral species). Include all
nonbonding electrons.
Select Draw Templates More
/
C H O
Erase
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