Mass spectral analysis of 1-cyclohexylpropan-2-one results in several fragmentation pathways. Complete the mechanism, and give the major products for the McLafferty rearrangement pathway. Include all nonbonding electrons and charges. H₂ H₂C H₂C. CH .H :0: CH3 -e radical cationic intermediate A McLafferty Rearrangement McLafferty Products Ring structures tool Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally delete a vital part of the structure, use the undo

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Mass spectral analysis of 1-cyclohexylpropan-2-one results in several fragmentation pathways. Complete the mechanism, and
give the major products for the McLafferty rearrangement pathway. Include all nonbonding electrons and charges.
H₂
C.
H
H₂C
H
H₂C.
CH
H₂
:O:
CH3
-e-
radical cationic
intermediate A
McLafferty
Rearrangement
McLafferty
Products
H₂
Ring structures tool
Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally delete a vital part of the structure, use the undo
button on the lower left of the drawing canvas.
Transcribed Image Text:Mass spectral analysis of 1-cyclohexylpropan-2-one results in several fragmentation pathways. Complete the mechanism, and give the major products for the McLafferty rearrangement pathway. Include all nonbonding electrons and charges. H₂ C. H H₂C H H₂C. CH H₂ :O: CH3 -e- radical cationic intermediate A McLafferty Rearrangement McLafferty Products H₂ Ring structures tool Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally delete a vital part of the structure, use the undo button on the lower left of the drawing canvas.
Add electrons and the charge for the resulting radical
cationic intermediate, and add curved arrows for the
McLafferty rearrangement mechanism.
Select Draw Templates More
H₂C
|
H₂C
III с H
H₂
C
H₂
CH
CH3
Erase
Draw the McLafferty rearrangement products (one
radical cation and one neutral species). Include all
nonbonding electrons.
Select Draw Templates More
/
C H O
Erase
Transcribed Image Text:Add electrons and the charge for the resulting radical cationic intermediate, and add curved arrows for the McLafferty rearrangement mechanism. Select Draw Templates More H₂C | H₂C III с H H₂ C H₂ CH CH3 Erase Draw the McLafferty rearrangement products (one radical cation and one neutral species). Include all nonbonding electrons. Select Draw Templates More / C H O Erase
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Knowledge Booster
Protection of Groups in Organic Synthesis
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY