HW10 #3

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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HW10 #3

Be sure to answer all parts.
Consider the cyclization reaction mechanism that is partially detailed below and predict the structures
of key intermediates. Only draw resonance structures with carbanions and not oxyanions.
CH₂OOC
CH₂0
:O:
HH
:0: :0:
Na+ :ỌCH3
↓
[1] NaOCH3
[2] H₂O
draw structure ...
↓
draw structure ...
↓i
H₂O
COOCH3
+ ÖH
COOCH3
+ CH3OH
Transcribed Image Text:Be sure to answer all parts. Consider the cyclization reaction mechanism that is partially detailed below and predict the structures of key intermediates. Only draw resonance structures with carbanions and not oxyanions. CH₂OOC CH₂0 :O: HH :0: :0: Na+ :ỌCH3 ↓ [1] NaOCH3 [2] H₂O draw structure ... ↓ draw structure ... ↓i H₂O COOCH3 + ÖH COOCH3 + CH3OH
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