Le Chatelier's principle (Sec. 9.9) considers the effects of outside forces on systems at chemical equilibrium. According to this principle, a stress applied to the system can favor the chemical reaction that will reduce the stress- either the forward reaction, in which case more product is formed, or the reverse reaction, in which case more reactants form. Some of the stresses that can cause this readjustment of the chemical equilibrium are concentration changes, temperature changes, and pressure changes. a. Indicate whether each change in conditions below would shift the chemical equilibrium of the following chemical reaction to the left or to the right: CH4(g) +2028) C02(g) + 2H20(g) + heat Equilibrium Change Change in conditions Explanation increasing the concentration of 02 increasing the temperature of the reaction introduction of an effective catalyst for this reaction increasing the pressure exerted on the reaction b. Indicate whether each change in conditions below would shift the equilibrium of the following chemical reaction to the left or to the right: N2(g) + 202(g) + heat Equilibrium Change Change in conditions Explanation increasing the concentration of 02 increasing the temperature of the reaction introduction of an effective catalyst for this reaction increasing the pressure exerted on the reaction

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Le Chatelier's principle (Sec. 9.9) considers the effects of outside forces on systems at
chemical equilibrium. According to this principle, a stress applied to the system can favor
the chemical reaction that will reduce the stress – either the forward reaction, in which case
more product is formed, or the reverse reaction, in which case more reactants form. Some of
the stresses that can cause this readjustment of the chemical equilibrium are concentration
changes, temperature changes, and pressure changes.
9.9
a. Indicate whether each change in conditions below would shift the chemical equilibrium of
the following chemical reaction to the left or to the right:
СH4(g) +20-(3)
CO2(g) + 2H20(g) + heat
Equilibrium
Change
Change in conditions
Explanation
increasing the
concentration of 02
increasing the temperature
of the reaction
introduction of an
effective catalyst for this
reaction
increasing the pressure
exerted on the reaction
b. Indicate whether each change in conditions below would shift the equilibrium of the
following chemical reaction to the left or to the right:
N2(g) + 202(g) + heat =
Equilibrium
Change
Change in conditions
Explanation
increasing the concentration
of 02
increasing the temperature
of the reaction
introduction of an effective
catalyst for this reaction
increasing the pressure
exerted on the reaction
Cengggo
publicly
02016
Learning. Ail Rights Reserved. May not be scanned, copied or duplicated, or posted to a
accessible website, whole or in part.
76
Chapter 9
Chemical Reactions
75
Self-rest
True-false: Indicate whether the following statements are true or false. If the statement is
false, give the word or phrase that may be substituted for the underlined portion to make
the statement true.
1. The reaction 2CUO * 2Cu + 02 is an example of a displacement reaction.
2. The oxidation number of a metal in its elemental state is always positive.
3. The oxidation number of oxygen in most compounds is-2.
4. A substance that is oxidized loses electrons.
5. A reducing agent gains electrons.
6. Adding heat to an endothermic reaction helps the reaction to go toward the products
side.
7. The addition of a catalyst will not change the equilibrium position of a chemical reaction.
8. The rate of a reaction is not affected by the addition of a catalyst.
9. Increasing the concentration of products in a chemical equilibrium reaction shifts the
equilibrium toward the product side of the reaction.
10. In a chemical equilibrium constant expression, the concentrations of the reactants are
found in the numerator.
I1. A large chemical equilibrium constant indicates that the equilibrium position is to the
right side.of the equation.
12. In chemical equilibrium constant expressions, concentrations of pure solids and pure
liquids remain constant.
Transcribed Image Text:4:25 13 Read Only - You can't save changes to this.. Le Chatelier's principle (Sec. 9.9) considers the effects of outside forces on systems at chemical equilibrium. According to this principle, a stress applied to the system can favor the chemical reaction that will reduce the stress – either the forward reaction, in which case more product is formed, or the reverse reaction, in which case more reactants form. Some of the stresses that can cause this readjustment of the chemical equilibrium are concentration changes, temperature changes, and pressure changes. 9.9 a. Indicate whether each change in conditions below would shift the chemical equilibrium of the following chemical reaction to the left or to the right: СH4(g) +20-(3) CO2(g) + 2H20(g) + heat Equilibrium Change Change in conditions Explanation increasing the concentration of 02 increasing the temperature of the reaction introduction of an effective catalyst for this reaction increasing the pressure exerted on the reaction b. Indicate whether each change in conditions below would shift the equilibrium of the following chemical reaction to the left or to the right: N2(g) + 202(g) + heat = Equilibrium Change Change in conditions Explanation increasing the concentration of 02 increasing the temperature of the reaction introduction of an effective catalyst for this reaction increasing the pressure exerted on the reaction Cengggo publicly 02016 Learning. Ail Rights Reserved. May not be scanned, copied or duplicated, or posted to a accessible website, whole or in part. 76 Chapter 9 Chemical Reactions 75 Self-rest True-false: Indicate whether the following statements are true or false. If the statement is false, give the word or phrase that may be substituted for the underlined portion to make the statement true. 1. The reaction 2CUO * 2Cu + 02 is an example of a displacement reaction. 2. The oxidation number of a metal in its elemental state is always positive. 3. The oxidation number of oxygen in most compounds is-2. 4. A substance that is oxidized loses electrons. 5. A reducing agent gains electrons. 6. Adding heat to an endothermic reaction helps the reaction to go toward the products side. 7. The addition of a catalyst will not change the equilibrium position of a chemical reaction. 8. The rate of a reaction is not affected by the addition of a catalyst. 9. Increasing the concentration of products in a chemical equilibrium reaction shifts the equilibrium toward the product side of the reaction. 10. In a chemical equilibrium constant expression, the concentrations of the reactants are found in the numerator. I1. A large chemical equilibrium constant indicates that the equilibrium position is to the right side.of the equation. 12. In chemical equilibrium constant expressions, concentrations of pure solids and pure liquids remain constant.
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