Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as follows: 2A + В - 2C (all gases) The method of initial rates is used to determine the rate law for this reaction. JA], initial 0.0100 M 0.0200 M 0.0100 M [B], initial 0.0400 M 0.0200 M 0.0200 M Rate (M/sec) 7.5 x 10* 3.0х 107 7.5 x 10³ Experiment 3 The following four mechanisms can be considered along with the data given above. fast equilibrium slow a) A + D + C ½B + D → C b) А + A + в — D с + с slow D fast fast equilibrium slow c) A + A D + D ½B + D d) A + B + D + C A + C + D slow fast equilibrium

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Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as
follows:
2A + В - 2C
(all gases)
The method of initial rates is used to determine the rate law for this reaction.
JA], initial
0.0100 M
0.0200 M
0.0100 M
[B], initial
0.0400 M
0.0200 M
0.0200 M
Rate (M/sec)
7.5 x 10*
3.0х 107
7.5 x 10³
Experiment
3
The following four mechanisms can be considered along with the data given above.
fast equilibrium
slow
a) A + D + C
½B
+ D → C
b) А + A + в — D
с + с
slow
D
fast
fast equilibrium
slow
c) A + A
D + D
½B
+ D
d) A +
B + D + C
A
+ C + D
slow
fast equilibrium
Transcribed Image Text:Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as follows: 2A + В - 2C (all gases) The method of initial rates is used to determine the rate law for this reaction. JA], initial 0.0100 M 0.0200 M 0.0100 M [B], initial 0.0400 M 0.0200 M 0.0200 M Rate (M/sec) 7.5 x 10* 3.0х 107 7.5 x 10³ Experiment 3 The following four mechanisms can be considered along with the data given above. fast equilibrium slow a) A + D + C ½B + D → C b) А + A + в — D с + с slow D fast fast equilibrium slow c) A + A D + D ½B + D d) A + B + D + C A + C + D slow fast equilibrium
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