It is of interest to decide if an analytical separation of the metal ions can be effected by selective precipitation of carbonates from a solution that is 0.106 M in Fe* and 0.103 M in Ba?+. FECO3 Kp -3.50x10-1 BACO3 Kp - 8.10x109 To analyze this problem, answer the following questions. M (1) What carbonate concentration is needed to precipitate 99.9% of the metal that forms the least soluble carbonate? (2) When 99.9% of the least soluble carbonate has precipitated, will all of the metal that forms the more soluble carbonate still remain in solution?

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It is of interest to decide if an analytical separation of the metal ions can be effected by selective precipitation of carbonates from a
solution that is 0.106 M in Fe* and 0.103 M in Bat.
FECO3
Kp = 3.50x10-11
BaCO,
K = 8.10x109
To analyze this problem, answer the following questions.
M
(1) What carbonate concentration is needed to precipitate 99.9% of the metal that forms the least soluble carbonate?
(2) When 99.9% of the least soluble carbonate has precipitated, will all of the metal that forms the more soluble carbonate still remain
in solution?
Transcribed Image Text:It is of interest to decide if an analytical separation of the metal ions can be effected by selective precipitation of carbonates from a solution that is 0.106 M in Fe* and 0.103 M in Bat. FECO3 Kp = 3.50x10-11 BaCO, K = 8.10x109 To analyze this problem, answer the following questions. M (1) What carbonate concentration is needed to precipitate 99.9% of the metal that forms the least soluble carbonate? (2) When 99.9% of the least soluble carbonate has precipitated, will all of the metal that forms the more soluble carbonate still remain in solution?
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