In x-ray studies of crystalline peptides, Linus Pauling and Robert Corey found that the C-N bond in the peptide link is intermediate in length (1.32 Å) between a typical C-N single bond (1.49 Å) and a C=N double bond (1.27 Å). They also foun that the peptide bond is planar (all four atoms attached to the C-N group are located in the same plane) and that the two a-carbon atoms attached to the C-N are always trans to each other (on opposite sides of the peptide bond). What does the length of the C-N bond in the peptide linkage indicate about its strength (i.e., whether it is single, double, or triple)? The C-N peptide bond has similar strength to a C=N bond. The C-N peptide bond is stronger than a C=N bond. The C-N peptide bond has similar strength to a C—N single bond. The C-N peptide bond is stronger than a C-N single bond.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter23: Carbon: Not Just Another Element
Section: Chapter Questions
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20 In x-ray studies of crystalline peptides, Linus Pauling and Robert Corey found that the C-N bond in the peptide link is
intermediate in length (1.32 Å) between a typical C-N single bond (1.49 Å) and a C=N double bond (1.27 Å). They also found
that the peptide bond is planar (all four atoms attached to the C-N group are located in the same plane) and that the two
a-carbon atoms attached to the C-N are always trans to each other (on opposite sides of the peptide bond).
What does the length of the C-N bond in the peptide linkage indicate about its strength (i.e., whether it is single, double,
or triple)?
The C-N peptide bond has similar strength to a C=N bond.
The C-N peptide bond is stronger than a C=N bond.
The C-N peptide bond has similar strength to a C-N single bond.
The C-N peptide bond is stronger than a C-N single bond.
Transcribed Image Text:20 In x-ray studies of crystalline peptides, Linus Pauling and Robert Corey found that the C-N bond in the peptide link is intermediate in length (1.32 Å) between a typical C-N single bond (1.49 Å) and a C=N double bond (1.27 Å). They also found that the peptide bond is planar (all four atoms attached to the C-N group are located in the same plane) and that the two a-carbon atoms attached to the C-N are always trans to each other (on opposite sides of the peptide bond). What does the length of the C-N bond in the peptide linkage indicate about its strength (i.e., whether it is single, double, or triple)? The C-N peptide bond has similar strength to a C=N bond. The C-N peptide bond is stronger than a C=N bond. The C-N peptide bond has similar strength to a C-N single bond. The C-N peptide bond is stronger than a C-N single bond.
Macm
What do the observations of Pauling and Corey tell us about the ease of rotation about the C-N peptide bond?
The C-N peptide bond can rotate easily, providing flexibility to a protein structure.
The C-N peptide bond is important to protein structure and has limited rotation giving rise to the y angle.
The C-N peptide bond is important to protein structure and has limited rotation giving rise to the angle.
The C-N peptide bond does not rotate.
Transcribed Image Text:Macm What do the observations of Pauling and Corey tell us about the ease of rotation about the C-N peptide bond? The C-N peptide bond can rotate easily, providing flexibility to a protein structure. The C-N peptide bond is important to protein structure and has limited rotation giving rise to the y angle. The C-N peptide bond is important to protein structure and has limited rotation giving rise to the angle. The C-N peptide bond does not rotate.
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