In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)—(NH2)zCO(aq) the following data were obtained: [NH4NCO], M 0.948 minutes 0 0.474 131 0.237 392 0.119 911 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.948 M is starting concentration is 0.474 M is min. (3) Based on these data, the rate constant for this (2) The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is order reaction is M-¹ min-¹. M-¹ min ¹. min and when the M-¹ min ¹.
In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)—(NH2)zCO(aq) the following data were obtained: [NH4NCO], M 0.948 minutes 0 0.474 131 0.237 392 0.119 911 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.948 M is starting concentration is 0.474 M is min. (3) Based on these data, the rate constant for this (2) The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is order reaction is M-¹ min-¹. M-¹ min ¹. min and when the M-¹ min ¹.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)—(NH2)2CO(aq)
the following data were obtained:
[NH4NCO], M 0.948
minutes
0
0.474
131
0.237
392
0.119
911
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.948 M is
starting concentration is 0.474 M is
min.
(3)
Based on these data, the rate constant for this
(2)
The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is
The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is
order reaction is
M-¹ min ¹.
M-¹ min ¹.
min and when the
M-¹ min ¹.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb8d8ce1c-d1ae-4fbf-bbe3-121c6915374e%2F2a4eb542-852d-4e2c-93f3-99f6883da253%2F8c31x18_processed.jpeg&w=3840&q=75)
Transcribed Image Text:In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)—(NH2)2CO(aq)
the following data were obtained:
[NH4NCO], M 0.948
minutes
0
0.474
131
0.237
392
0.119
911
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.948 M is
starting concentration is 0.474 M is
min.
(3)
Based on these data, the rate constant for this
(2)
The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is
The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is
order reaction is
M-¹ min ¹.
M-¹ min ¹.
min and when the
M-¹ min ¹.
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