In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)—(NH2)zCO(aq) the following data were obtained: [NH4NCO], M 0.948 minutes 0 0.474 131 0.237 392 0.119 911 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.948 M is starting concentration is 0.474 M is min. (3) Based on these data, the rate constant for this (2) The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is order reaction is M-¹ min-¹. M-¹ min ¹. min and when the M-¹ min ¹.

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Chapter1: Chemical Foundations
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In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)—(NH2)2CO(aq)
the following data were obtained:
[NH4NCO], M 0.948
minutes
0
0.474
131
0.237
392
0.119
911
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.948 M is
starting concentration is 0.474 M is
min.
(3)
Based on these data, the rate constant for this
(2)
The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is
The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is
order reaction is
M-¹ min ¹.
M-¹ min ¹.
min and when the
M-¹ min ¹.
Transcribed Image Text:In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)—(NH2)2CO(aq) the following data were obtained: [NH4NCO], M 0.948 minutes 0 0.474 131 0.237 392 0.119 911 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.948 M is starting concentration is 0.474 M is min. (3) Based on these data, the rate constant for this (2) The average A(1/[NH4NCO]) / At from t = 0 min to t = 131 min is The average A(1/[NH4NCO]) / At from t = 131 min to t = 392 min is order reaction is M-¹ min ¹. M-¹ min ¹. min and when the M-¹ min ¹.
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