In a study of the gas phase decomposition of nitrosyl chloride at 400 K NOCI(g)- →NO(g) + ½ Cl2(g) the concentration of NOCI was followed as a function of time. It was found that a graph of 1/[NOCI] versus time in seconds gave a straight line with a slope of 8.26x104 M's1 and a y- intercept of 17.8 M-1. |order in NOCI M1 Based on this plot, the reaction is and the rate constant for the reaction is s-1.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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In a study of the gas phase decomposition of nitrosyl chloride
at 400 K
NOCI(g)
→NO(g) +½ Cl2(g)
the concentration of NOCI was followed as a function of time.
It was found that a graph of 1/[NOCI] versus time in seconds
gave a straight line with a slope of 8.26x104 M1s1 and a y-
intercept of 17.8 M-1.
Based on this plot, the reaction is |
v order in NOCI
and the rate constant for the reaction is
M1
s1.
Transcribed Image Text:In a study of the gas phase decomposition of nitrosyl chloride at 400 K NOCI(g) →NO(g) +½ Cl2(g) the concentration of NOCI was followed as a function of time. It was found that a graph of 1/[NOCI] versus time in seconds gave a straight line with a slope of 8.26x104 M1s1 and a y- intercept of 17.8 M-1. Based on this plot, the reaction is | v order in NOCI and the rate constant for the reaction is M1 s1.
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