Account for the relative values of the rate constants for the following outer sphere electron-transfer reactions by considering reorganization energy and driving force. Be sure to state which reactions have AG° = 0. %3D Reaction Reactants k/ dm3 mol-1 s1 [Ru(NH3)6]3+ + [Ru(NH3)6]?* [Co(NH3)6]³* + [Ru(NH3)6]²* [Co(NH3)6]³+ + [Co(NH3)6]?* 104 II 10-2 II 10-6
Account for the relative values of the rate constants for the following outer sphere electron-transfer reactions by considering reorganization energy and driving force. Be sure to state which reactions have AG° = 0. %3D Reaction Reactants k/ dm3 mol-1 s1 [Ru(NH3)6]3+ + [Ru(NH3)6]?* [Co(NH3)6]³* + [Ru(NH3)6]²* [Co(NH3)6]³+ + [Co(NH3)6]?* 104 II 10-2 II 10-6
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
![Account for the relative values of the rate constants for the following outer sphere
electron-transfer reactions by considering reorganization energy and driving force. Be sure to state which
reactions have AG° = 0.
%3D
Reaction
Reactants
k/ dm3 mol-1 s1
[Ru(NH3)6]3+ + [Ru(NH3)6]?*
[Co(NH3)6]³* + [Ru(NH3)6]²*
[Co(NH3)6]³+ + [Co(NH3)6]?*
104
II
10-2
II
10-6](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff92d0bbc-a351-41e8-b658-700f33c71c59%2F56ff0da4-eda6-45ab-bb95-3b8386c7140a%2F6hesmb8_processed.png&w=3840&q=75)
Transcribed Image Text:Account for the relative values of the rate constants for the following outer sphere
electron-transfer reactions by considering reorganization energy and driving force. Be sure to state which
reactions have AG° = 0.
%3D
Reaction
Reactants
k/ dm3 mol-1 s1
[Ru(NH3)6]3+ + [Ru(NH3)6]?*
[Co(NH3)6]³* + [Ru(NH3)6]²*
[Co(NH3)6]³+ + [Co(NH3)6]?*
104
II
10-2
II
10-6
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