In a coffee cup calorimeter, 50.0 mL of 0.100 M AgNO3 and 50.0 mL of 0.100 M HCl are mixed. The following reaction occurs: Ag+ (aq) + Cl– (aq) ⟶ AgCl(s) If the two solutions are each initially at 22.60°C, and if the final temperature is 23.40°C, calculate ΔH for the reaction in kJ/mol of AgCl formed. Assume a mass of 100.0 g for the combined solution and a specific heat capacity of 4.184 J °C–1g^–1.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
In a coffee cup calorimeter, 50.0 mL of 0.100 M AgNO3 and 50.0 mL of 0.100 M HCl are mixed. The following reaction occurs:
Ag+ (aq) + Cl– (aq) ⟶ AgCl(s)
If the two solutions are each initially at 22.60°C, and if the final temperature is 23.40°C, calculate ΔH for the reaction in kJ/mol of AgCl formed. Assume a mass of 100.0 g for the combined solution and a specific heat capacity of 4.184 J °C–1g^–1.
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