Consider the reaction: СаСОз{(s) —СаО(9) + СO2(g) Using standard thermodynamic data at 298K, calculate the free energy change when 2.20 moles of CaCO3(s) react at standard conditions. AG°, kJ rxn

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Calcium ΔHof (kJ/mol) ΔGof (kJ/mol) So (J/mol K)

Ca (s)

0

0

41.4

Ca (g)

178.2

144.3

158.9

Ca2+ (g)

1925.9

   

CaC2 (s)

-59.8

-64.9

70.0

CaCO3 (s, calcite)

-1206.9

-1128.8

92.9

CaCl2 (s)

-795.8

-748.1

104.6

CaF2 (s)

-1219.6

-1167.3

68.9

CaH2 (s)

-186.2

-147.2

42.0

CaO (s)

-635.1

-604.0

39.8

CaS (s)

-482.4

-477.4

56.5

Ca(OH)2 (s)

-986.1

-898.5

83.4

Ca(OH)2 (aq)

-1002.8

-868.1

-74.5

Ca3(PO4)2 (s)

-4126.0

-3890.0

241.0

CaSO4 (s)

-1434.1

-1321.8

106.7

CaSiO3 (s)

-1630.0

-1550.0

84.0

 

 

 

Carbon ΔHof (kJ/mol) ΔGof (kJ/mol) So (J/mol K)

C (s, graphite)

0

0

5.7

C (s, diamond)

1.9

2.9

2.4

C (g)

716.7

671.3

158.1

CCl4 (l)

-135.4

-65.2

216.4

CCl4 (g)

-102.9

-60.6

309.9

CHCl3 (l)

-134.5

-73.7

201.7

CHCl3 (g)

-103.1

-70.3

295.7

CH4 (g)

-74.8

-50.7

186.3

CH3OH (g)

-200.7

-162.0

239.8

CH3OH (l)

-238.7

-166.3

126.8

H2CO (g)

-116.0

-110.0

219.0

HCOOH (g)

-363.0

-351.0

249.0

HCN (g)

135.1

125.0

202.0

C2H2 (g)

226.7

209.2

200.9

C2H4 (g)

52.3

68.2

219.6

CH3CHO (g, acetaldehyde)

-166.0

-129.0

250.0

C2H4O (g, ethylene oxide)

-53.0

-13.0

242.0

CH3CH2OH (l)

-277.7

-174.8

160.7

CH3CH2OH (g)

-235.1

-168.5

282.7

CH3COOH (l)

-484.0

-389.0

160.0

C2H6 (g)

-84.7

-32.8

229.6

C3H6 (g)

20.9

62.7

266.9

C3H8 (g)

-103.8

-23.5

269.9

CH2=CHCN (l)

152.0

190.0

274.0

C6H6 (l)

49.0

124.5

172.8

C6H12O6 (s)

-1275.0

-911.0

212.0

CO (g)

-110.5

-137.2

197.7

CO2 (g)

-393.5

-394.4

213.7

CS2 (g)

117.4

67.1

237.8

COCl2 (g)

-218.8

-204.6

283.5

Consider the reaction:
СаСОз{(s) —СаО(9) + СO2(g)
Using standard thermodynamic data at 298K, calculate the free energy change when 2.20 moles of CaCO3(s) react at standard conditions.
AG°,
kJ
rxn
Transcribed Image Text:Consider the reaction: СаСОз{(s) —СаО(9) + СO2(g) Using standard thermodynamic data at 298K, calculate the free energy change when 2.20 moles of CaCO3(s) react at standard conditions. AG°, kJ rxn
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