Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 1. MF C;H,NO L00 50 IR KBr Disc 4D00 3000 1500 1000 so 2000 SDO NAVENUMBERI - 3328 13 3156 79 3087 3066 2940 72 2902 1639 1494 36 1166 60 801 79 718 36 710 23 698 26 671 62 79 1448 70 1151 74 74 1409 35 60 66 1617 44 1604 36 1362 72 57 1334 1036 74 999 79 937 74 3054 3004 77 1579 15 1664 1911 32 831 79 807 74 646 53 2962 79 1303 47 617 70
Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 1. MF C;H,NO L00 50 IR KBr Disc 4D00 3000 1500 1000 so 2000 SDO NAVENUMBERI - 3328 13 3156 79 3087 3066 2940 72 2902 1639 1494 36 1166 60 801 79 718 36 710 23 698 26 671 62 79 1448 70 1151 74 74 1409 35 60 66 1617 44 1604 36 1362 72 57 1334 1036 74 999 79 937 74 3054 3004 77 1579 15 1664 1911 32 831 79 807 74 646 53 2962 79 1303 47 617 70
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.37P
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Question
![Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant
fragments. Suggest possible structure based on MS and IR data.
1. MF C3H,NO
LOD
IR KBr Disc
4000
3000
2000
1500
1000
50D0
HAVENUMB ERI -1l
3328
13
2940 72
601 79
1494
1448 70
36
1166
60
74
3156 79
2902 79
1151
718 36
3087 74
3066 60
3054 66
1639
1617
1604
1036
999
1409
33
72
4
74
710 23
1362
79
698 26
671
62
44
36
1334
57
937
74
3004
32
831
807
77
1579 15
1664
1911
E0E I
47
79
74
646 53
617
70
2962 79
TFINSHETTANCET1](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc1955cf1-53cb-48f7-ac28-5ffbb152c656%2F8cce207d-072f-4cd8-aee7-cd1022aba270%2Fbsn40z_processed.png&w=3840&q=75)
Transcribed Image Text:Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant
fragments. Suggest possible structure based on MS and IR data.
1. MF C3H,NO
LOD
IR KBr Disc
4000
3000
2000
1500
1000
50D0
HAVENUMB ERI -1l
3328
13
2940 72
601 79
1494
1448 70
36
1166
60
74
3156 79
2902 79
1151
718 36
3087 74
3066 60
3054 66
1639
1617
1604
1036
999
1409
33
72
4
74
710 23
1362
79
698 26
671
62
44
36
1334
57
937
74
3004
32
831
807
77
1579 15
1664
1911
E0E I
47
79
74
646 53
617
70
2962 79
TFINSHETTANCET1
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