Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 2. MF C₂H₂O 131(Base peak 27.0 1.5 78.0 1.1 100 39.M 1.0 38.A 1.7 30.0 3.7 50.0 0.6 51.0 21.2 80 1.1 52.0 5.5 52.0 1.2 54.0 1.0 55.0 1.1 61.A 1.1 60 62.A 2.5 63.0 5.7 65.0 1.1 M.H 5.5 14.1 4. / 16.0 5.1 40 77 77.0 35.7 78.0 20.1 79.0 1./ 51 29.0 1.2 91.0 2.5 20 101.0 1.5 102.0 51.5 104. A 27.4 105.0 3.5 131.0 108.0 132.0 74.8 141.4 75 m/z Relative Intensity 0-t 25 50 103 100 T|||| ™m 125 132(M+) 133(M+1) 150

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Chapter1: Chemical Foundations
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Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant
fragments. Suggest possible structure based on MS and IR data.
2. MF C₂H₂O
131(Base peak
27.9
1.5
28.0
1.1
100
3.M
1.60
38.A
1.7
30.0
3.7
50.0
51.0
21.2
80
1.1
52.0
5.5
53.0
1.2
54.0
1.0
55.9
1.1
61.A
1.1
62.8
2.5
63.9
5.7
65.0
1.1
M.H
14.4
16.0
5.1
77
77.0
51
91.0
101.0
102.0
103.0
184.8
185.0
131.0
132.0
141.4
Relative Intensity
40
20
Other
25
50
75
103
||||||||
100
m/z
|||||||
125
132(M+)
133(M+1)
150
35.7
20.1
1./
1.2
2.5
1.5
51.5
27.4
3.5
108.0
71.8
Transcribed Image Text:Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 2. MF C₂H₂O 131(Base peak 27.9 1.5 28.0 1.1 100 3.M 1.60 38.A 1.7 30.0 3.7 50.0 51.0 21.2 80 1.1 52.0 5.5 53.0 1.2 54.0 1.0 55.9 1.1 61.A 1.1 62.8 2.5 63.9 5.7 65.0 1.1 M.H 14.4 16.0 5.1 77 77.0 51 91.0 101.0 102.0 103.0 184.8 185.0 131.0 132.0 141.4 Relative Intensity 40 20 Other 25 50 75 103 |||||||| 100 m/z ||||||| 125 132(M+) 133(M+1) 150 35.7 20.1 1./ 1.2 2.5 1.5 51.5 27.4 3.5 108.0 71.8
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