Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 2. MF C₂H₂O 131(Base peak 27.09 4.5 28.0 100- 1.1 1.0 38.0 1.2 30.0 3.7 50.0 8.G 52.0 21.2 80 1.1 52.0 5.5 53.0 1.2 54.0 1.0 55.0 1.1 61.A 1.1 60 62.A 2.5 63.9 5.7 65.0 4.2 M.M 5.5 4./ 77 16.0 5.1 77.0 35.7 26.1 78.0 79.0 1./ 51 ww. 01.0 2.5 101.0 1.5 102.0 8.9 109.0 54.5 104.9 27.4 105.9 3.5 131.0 100.0 0-mm mm 132.0 74.8 25 50 100 141.4 125 150 m/z Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 2. MF C₂H₂O IR KBr Disc LOD www.m 50 3000 4500 1000 500 HAVENUE CRI Relative Intensity 6 40 20 D 4000 3332 77 2744 64 3322 79 2716 74 3065 85 1677 4 3040 70 1627 14 3029 63 1606 49 2992 74 1597 55 60 1676 47 75 2008 74 66 55 1496 66 1204 1450 34 LJ 79 1395 24 LJ 50 1329 74 LJ 26 9 1306 66 LO79 SB 1290 52 LOOD 52 1262 62 973 27 646 79 748 19 689 25 620 74 606 60 564 49 60L 61 103 132(M+) 133(M+1)
Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 2. MF C₂H₂O 131(Base peak 27.09 4.5 28.0 100- 1.1 1.0 38.0 1.2 30.0 3.7 50.0 8.G 52.0 21.2 80 1.1 52.0 5.5 53.0 1.2 54.0 1.0 55.0 1.1 61.A 1.1 60 62.A 2.5 63.9 5.7 65.0 4.2 M.M 5.5 4./ 77 16.0 5.1 77.0 35.7 26.1 78.0 79.0 1./ 51 ww. 01.0 2.5 101.0 1.5 102.0 8.9 109.0 54.5 104.9 27.4 105.9 3.5 131.0 100.0 0-mm mm 132.0 74.8 25 50 100 141.4 125 150 m/z Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 2. MF C₂H₂O IR KBr Disc LOD www.m 50 3000 4500 1000 500 HAVENUE CRI Relative Intensity 6 40 20 D 4000 3332 77 2744 64 3322 79 2716 74 3065 85 1677 4 3040 70 1627 14 3029 63 1606 49 2992 74 1597 55 60 1676 47 75 2008 74 66 55 1496 66 1204 1450 34 LJ 79 1395 24 LJ 50 1329 74 LJ 26 9 1306 66 LO79 SB 1290 52 LOOD 52 1262 62 973 27 646 79 748 19 689 25 620 74 606 60 564 49 60L 61 103 132(M+) 133(M+1)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Transcribed Image Text:Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant
fragments. Suggest possible structure based on MS and IR data.
2. MF C₂H₂O
131(Base peak
27.0
1.5
28.0
100
1.0
38.8
30.0
3.7
50.0
8.G
21.2
80
1.1
52.0
5.5
52.0
1.2
54.0
1.0
55.0
1.1
61.A
1.1
60
62.A
2.5
63.9
5.7
1.2
65.0
M.M
1.1
16.8
5.1
40
77
77.0
35.7
78.0
20.1
19.0
1./
51
01.0
2.5
20
101.0
1.5
102.0
8.9
54.5
133(M+1)
104. A
27.4
105.0
3.5
131.0
103.0
0 ttttm
t
www.t
132.0
74.8
141.
25
50
100
125
150
m/z
Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant
fragments. Suggest possible structure based on MS and IR data.
2. MF C₂H₂O IR KBr Disc
LOD
v
wym
50
3000
15.00
1000
500
HAVENUE CRI
Relative Intensity
D
4000
3332 77 2744 64
3322 79 2716 74
3063 85 1677 4
3040 70 1627 14
3029
1606 49
2992 74
1587 55
2014 60 1676 47
1496 66
1450 34
1395 74
1329 74
1306 86
1295 52
1262
75
2008
1204
74
LJ 79 66
L150 55
LJ 26
9
LO73 58
LOOD 52
973 27
846 79
748 19
689 25
620 74
606 60
504 49
60L 614
103
132(M+)
3/5
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