Don't used Ai solution Identify the most likely second-row transition metal for each of the following (show all your calculations)(Cp-cyclopentadiene, en = ethylenediamine):a. [M(en)2(NO)2]+(contains linear M-N-O)b. [(n³-C3H5)(n-C6H6)M(CN)]c. M(CO)(PMe3)2Cl(square planar complex)d. (n-Cp)MCp(CO)

Approach to solving the question:Neutral electron count method. Detailed explanation:The first…

Answered: Identify the most likely second-row…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 53AP

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a. In the absorption spectrum of the complex ion Cr(NCS)63, there is a band corresponding to the absorption of a photon of light with an energy of 1.75 104 cm-1. Given 1 cm1 = 1.986 1023 J, what is the wavelength of this photon? b. The CrNC bond angle in Cr(NCS)63 is predicted to be 180. What is the hybridization of the N atom in the Ncs- ligand when a Lewis acid-base reaction occurs between Cr3+ and NCs- that would give a 180 CrNC bond angle? Cr(NCS)63 undergoes substitution by ethylenediamine (en) according to the equation Cr(NCS)63+2enCr(NCS)2(en)2++4NCS Does Cr(NCS)2(en)2+ exhibit geometric isomerism? Does Cr(NCS)2(en)2+ exhibit optical isomerism?
Give the coordination numbers and write the formulas for each of the following, including all isomers where appropriate: (a) tetrahydroxozincate(ll) ion (tetrahedral). (b) hexacyanopalladate(IV) ion. (c) dichlomaurate(I) ion (note that aurum is Latin for "gold"). (d) diamminedichloroplatinum(Il). (e) potassium diamminetetrachlorochromate(III). (f) hexaamminecobalt(III) hexacyanochromate(III). (g) dibromobis(ethylenediamine) cobalt(III) nitrate
A. Based on the 18-electron rule, identify the first-row transition metal for each of the following: H3CM(CO)5 (η3-C3H5)(η5-C5H5)M(CH3)(NO) (has a linearly coordinated NO) [M(CO)4I(diphos)]-
Identify the first-row transition metal for the following 18-electron species: a. [M(CO)3(PPh3)]¯¯ c. (n*-CgHg)M(CO), b. HM(CO)5 d. [(n-C5H5)M(CO)3]2 (assume single M-M bond)
Identify the optically active compounds from the following: Select one: O O a. [Cr (NH3)5Cl] + b. cis- [Co(en)₂Cl₂] 3+ c. [Co(NH3) ] d. trans- [Co(en)₂Cl₂]¹ +
2. You have prepared a sample of [Co(en)3]Br3 (en = H₂NCH₂CH₂NH₂). Which technique is best suited to confirming that the metal ion is in an octahedral environment in the solid state? A) ¹H NMR spectroscopy B) ESI MS C) Moessbauer spectroscopy D) single crystal XRD
Based on the 18-electron rule, determine the expected charge on the following: a. [Co(CO)3]zb. [Ni(CO)3(NO)]zc. [(η3-C3H5)V(CNCH3)5]z
Identify the first row transition metal that satisfies the requirements given:a. [M(H2O)6]2+ having two unpaired electrons (list all possibilities).b. [M(NH3)6]3+ that may have splitting of spin-allowed absorption band as a consequence of distortion of excited state (provide one example).c. [M(H2O)6]2+ expected to have the palest color in aqueous solution.
1. What is the CFSE of [Co(en)3]3+ (note: en is a strong field ligand)
8. Which of the following compounds will show Jahn-Teller distortion? [Mn(H₂O)]²+ [Mn(H₂O)]³+ [Cr(H₂O) [Fe(CN).] Draw the electronic energy levels without distortion, as well as after Jahn-Teller compression and extension and note the number of unpaired electrons in each case.
Chemistry 2. Predict the transition metal-containing products of the following reactions and label which type of organometallic reaction occurred. a. [Mn(CO)s] + H₂C=CH-CH₂Cl → b. trans-Ir(CO)CI(PPH3)2 + CH₂ → c. (n-C3Hs)Fe(CO)(CH3)+PPhy > d. H₂C-Mn(CO)s + SO₂ → e. W(CO) + CeHsLi → f. Fe(CO)s + NaCsHs →
2. Which of the following octahedral complexes are chiral: cis-[CoCl₂(en)2]*, [Cr(ox)3]³-, trans- [PtCl2(en)2]2+, [Ni(phen)3]²+, [RuBr4(phen)], cis-[RuCl(py)(phen)2]+ ?

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Identify the most likely second-row transition metal for each of the following (show all your calculations) (Cp-cyclopentadiene, en = ethylenediamine): a. [M(en)2(NO)2]+ (contains linear M-N-O) b. [(n³-C3H5)(n-C6H6)M(CN)] c. M(CO)(PMe3)2Cl (square planar complex) d. (n-Cp)MCp(CO)