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- In the Lewis structure for chloromethane, the chlorine atom is sharing _____ electron pair and “owns” _____ of those electrons. Also, the chlorine atom possesses two electrons from each of _____ unshared pairs. The total number of electrons that belong to chlorine is 7 . Chlorine is a Group ____ element. The formal charge on chlorine in chloromethane is ____.The Lewis structure of acetone is Circling the carbonyl carbon, i.e., the carbon atom attached to oxygen, and its octet gives Circling the oxygen atom and its octet gives Thus, atoms share electrons in making bonds, and a pair of electrons may be included in the octet of two different atoms. When computing the formal charge on an atom, the number of electrons that belong to that atom is compared with the number of electrons the atom would have in the unbonded and neutral state. If the two numbers are the same, the formal charge on the atom is zero. In a Lewis structure both electrons in an unshared pair belong to the atom, and one of every pair of shared (bonding) electrons belongs to the atom.A stable triatomic molecule can be formed that contains one atom each of nitrogen, sulfur, and fluorine. Three bonding structures are possible, depending on which is the central atom: NSF, SNF, and SFN. (a) Write a Lewis diagram for each of these molecules, indicating the formal charge on each atom. (b) Often, the structure with the least separation of formal charge is the most stable. Is this statement consistent with the observed structure for this molecule—namely, NSF, which has a central sulfur atom? (c) Does consideration of the electronegativities of N, S, and F from Figure 3.18 help rationalize this observed structure? Explain.
- Carbon monoxide (CO) is an example of an overall neutral molecule (netcharge=0) that hasnon-zero formal charges. Draw a Lewis structure of carbon monoxide (CO).The molecular ion S3N3 has the cyclic structure All SN bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is 0.375 and on each S atom is +0.041 . Show that this result is consistent with the overall +1 charge on the molecular ion.The oxygen atom in acetone possesses ____ unshared pairs and ____ shared pairs of electrons. The number of electrons that belong to oxygen is ____. Oxygen is a Group ____ element. The formal charge on oxygen in acetone is ____.
- A complete Lewis structure must show all nonzero formal charges. Complete each of thefollowing Lewis structures by adding any missing formal charges.the formal charges on all the atoms in the following Lewis diagrams. Which one would best represent bonding in the molecule Cl2O ?Explain why this Lewis structure for CO is not as valid as the Lewis structure you drew in theprevious question even though it has no “hot spots” of + or charge (formal charges).
- a.)Draw a Lewis diagram for IO4- in which the central I atom has a formal charge of zero and show all NONZERO formal charges on all atoms. note overall charge of ion is -1 b.)Draw a Lewis structure for IO4- in which the octet rule is satisfied on all atoms and show all NONZERO formal charges on all atoms. C.Based on formal charge, what is the best Lewis structure for the ion? smallest formal charge or octet rule satisfied for all atomsDraw the best Lewis structure for the following polyatomic ion and be sure to include all resonance structures and formal charges. Hint: Chlorine is the central atom. chlorate, ClO3Draw Lewis structure(s) for the acetate ion (CH2CO0). If there are equivalent resonance structures, draw all of them. • Draw one structure per sketcher box, and separate added sketcher boxes with the Do not include overall ion charges or formal charges in your drawing. • Do not draw double bonds to oxygen unless they are needed in order for the central atom to obey the octet rule. symbol. CH3COO":