i) In Table 1 (column 3) determine the number of 1H NMR peaks (ignore splitting) that you would expect for each of the above (hint: the no. of different proton environments) and ii) (column 4) predict the simple splitting pattern for each type of proton.
i) In Table 1 (column 3) determine the number of 1H NMR peaks (ignore splitting) that you would expect for each of the above (hint: the no. of different proton environments) and ii) (column 4) predict the simple splitting pattern for each type of proton.
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter5: Signals And Noise
Section: Chapter Questions
Problem 5.11QAP
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Q2. i) In Table 1 (column 3) determine the number of 1H NMR peaks (ignore splitting) that you would expect for each of the above (hint: the no. of different proton environments) and ii) (column 4) predict the simple splitting pattern for each type of proton.
![Structural
Isomers of
butanol
1-butanol
(Example)
2-butanol
2-methyl-1-
propanol
tert-butanol
HO
HO
OH
OH
Structure
(Ctrl) -
No. of
expected ¹H
NMR peaks
(Total 1
mark)
5
Expected splitting
patterns of ¹H NMR
peaks
(i.e. singlet(s),
doublet(d), multiplet(m)
etc.,)
(Total 2 marks)
CH3CH2CH2CH2-OH br(s)
CH3CH2CH2CH2-OH (t)
CH3CH2CH2CH2-OH (m)
CH3CH2CH2CH2-OH (m)
CH3CH2CH2CH2-OH (t)
Note: the CH3CH2CH2CH2-OH
hydrogen atom rapidly
exchanges and as a
consequence, ignore coupling to
this atom.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe911ac87-a4e8-4d2c-acf8-30bc708ca138%2F1631faf5-6962-4264-997c-e2785ffa8949%2Fhqwlwm_processed.png&w=3840&q=75)
Transcribed Image Text:Structural
Isomers of
butanol
1-butanol
(Example)
2-butanol
2-methyl-1-
propanol
tert-butanol
HO
HO
OH
OH
Structure
(Ctrl) -
No. of
expected ¹H
NMR peaks
(Total 1
mark)
5
Expected splitting
patterns of ¹H NMR
peaks
(i.e. singlet(s),
doublet(d), multiplet(m)
etc.,)
(Total 2 marks)
CH3CH2CH2CH2-OH br(s)
CH3CH2CH2CH2-OH (t)
CH3CH2CH2CH2-OH (m)
CH3CH2CH2CH2-OH (m)
CH3CH2CH2CH2-OH (t)
Note: the CH3CH2CH2CH2-OH
hydrogen atom rapidly
exchanges and as a
consequence, ignore coupling to
this atom.
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