● ● ● ● Add in the missing hydrogens Determine the number of ¹H NMR signals in each compound below. Label each type of proton (A, B, etc.) and fill in the tables provided on the following page with a row for each type of proton (signal). Predict the integration (#H's), the chemical shift range (ppm), and calculated chemical shift (ppm), that you would expect for each signal. Determine the splitting pattern for each signal using the n+1 rule, where n is the number of H's on adjacent carbon atoms. ● O ● ■ Sketch the predicted ¹H NMR spectrum of each compound and use nmrdb.org to check your work Approximate the central chemical shift of the signal on the x-axis and draw each splitting pattern. Don't worry about incorporating integration (peak size). (c) (a) Br ■ Splitting patterns: singlet, doublet, triplet, quartet, pentet, sextet, heptet, or multiplet. There is no splitting through heteroatoms (O, N, S, etc.) - all OH's are singlets! Br (e) (b) OH (f) (d) -OH
● ● ● ● Add in the missing hydrogens Determine the number of ¹H NMR signals in each compound below. Label each type of proton (A, B, etc.) and fill in the tables provided on the following page with a row for each type of proton (signal). Predict the integration (#H's), the chemical shift range (ppm), and calculated chemical shift (ppm), that you would expect for each signal. Determine the splitting pattern for each signal using the n+1 rule, where n is the number of H's on adjacent carbon atoms. ● O ● ■ Sketch the predicted ¹H NMR spectrum of each compound and use nmrdb.org to check your work Approximate the central chemical shift of the signal on the x-axis and draw each splitting pattern. Don't worry about incorporating integration (peak size). (c) (a) Br ■ Splitting patterns: singlet, doublet, triplet, quartet, pentet, sextet, heptet, or multiplet. There is no splitting through heteroatoms (O, N, S, etc.) - all OH's are singlets! Br (e) (b) OH (f) (d) -OH
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
please do d, e, and f
![1. Predict the ¹H NMR spectrum for compounds (b) - (f) below.
Add in the missing hydrogens
Determine the number of ¹H NMR signals in each compound below.
Label each type of proton (A, B, etc.) and fill in the tables provided on the following page with a row for
each type of proton (signal).
Predict the integration (#H's), the chemical shift range (ppm), and calculated chemical shift (ppm),
that you would expect for each signal.
Determine the splitting pattern for each signal using the n+1 rule, where n is the number of H's
on adjacent carbon atoms.
O
Splitting patterns: singlet, doublet, triplet, quartet, pentet, sextet, heptet, or multiplet.
There is no splitting through heteroatoms (O, N, S, etc.) - all OH's are singlets!
Sketch the predicted ¹H NMR spectrum of each compound and use nmrdb.org to check your work
Approximate the central chemical shift of the signal on the x-axis and draw each splitting pattern.
Don't worry about incorporating integration (peak size).
(c)
(a) Br
■
.
Br
(e)
(b)
OH
O
(d)
-OH](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F38a9992d-9c05-40da-9474-aaafff450dc4%2Fa9c7a6b4-ce64-4a50-b1fb-bb05e8063229%2Fypzudx_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1. Predict the ¹H NMR spectrum for compounds (b) - (f) below.
Add in the missing hydrogens
Determine the number of ¹H NMR signals in each compound below.
Label each type of proton (A, B, etc.) and fill in the tables provided on the following page with a row for
each type of proton (signal).
Predict the integration (#H's), the chemical shift range (ppm), and calculated chemical shift (ppm),
that you would expect for each signal.
Determine the splitting pattern for each signal using the n+1 rule, where n is the number of H's
on adjacent carbon atoms.
O
Splitting patterns: singlet, doublet, triplet, quartet, pentet, sextet, heptet, or multiplet.
There is no splitting through heteroatoms (O, N, S, etc.) - all OH's are singlets!
Sketch the predicted ¹H NMR spectrum of each compound and use nmrdb.org to check your work
Approximate the central chemical shift of the signal on the x-axis and draw each splitting pattern.
Don't worry about incorporating integration (peak size).
(c)
(a) Br
■
.
Br
(e)
(b)
OH
O
(d)
-OH
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
Step 1
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 4 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY