1. For the following molecules, find the number of unique proton signals that would be observed in ¹H NMR. Label the equivalent protons and give the multiplicity and integration for each. See the example for methyl ethyl ketone. Please note that singlet or multiplicity 1 are both acceptable answers.
1. For the following molecules, find the number of unique proton signals that would be observed in ¹H NMR. Label the equivalent protons and give the multiplicity and integration for each. See the example for methyl ethyl ketone. Please note that singlet or multiplicity 1 are both acceptable answers.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![1. For the following molecules, find the number of unique proton signals that would be
observed in ¹H NMR. Label the equivalent protons and give the multiplicity and
integration for each. See the example for methyl ethyl ketone. Please note that singlet or
multiplicity 1 are both acceptable answers.
Example:
H3C
H3C.
H₂
H3C.
CH3
H3C C -CH₂
CH3
H3C)
A
CH₂Cl2
OH
-Br
CH3
H₂
CH3
CH3
с
H₂
B
CH3
с
2. The following set of molecules each show a singlet. The chemical shifts (ppm) are 0.232,
3.052, 5.297 and 7.256. Match the shift to each molecule below.
A: Singlet (Multiplicity 1) Integration 3
B: Quartet (Multiplicity 4) Integration 2
C: Triplet (Multiplicity 3) Integration 3
CHC13
CH,C1
CH4](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa48a364c-7fba-48af-a99c-dde576f334b1%2F4b5bf59c-f731-454d-9fd2-8845dee07826%2F38epf5i_processed.png&w=3840&q=75)
Transcribed Image Text:1. For the following molecules, find the number of unique proton signals that would be
observed in ¹H NMR. Label the equivalent protons and give the multiplicity and
integration for each. See the example for methyl ethyl ketone. Please note that singlet or
multiplicity 1 are both acceptable answers.
Example:
H3C
H3C.
H₂
H3C.
CH3
H3C C -CH₂
CH3
H3C)
A
CH₂Cl2
OH
-Br
CH3
H₂
CH3
CH3
с
H₂
B
CH3
с
2. The following set of molecules each show a singlet. The chemical shifts (ppm) are 0.232,
3.052, 5.297 and 7.256. Match the shift to each molecule below.
A: Singlet (Multiplicity 1) Integration 3
B: Quartet (Multiplicity 4) Integration 2
C: Triplet (Multiplicity 3) Integration 3
CHC13
CH,C1
CH4
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