1. For the following molecules, find the number of unique proton signals that would be observed in ¹H NMR. Label the equivalent protons and give the multiplicity and integration for each. See the example for methyl ethyl ketone. Please note that singlet or multiplicity 1 are both acceptable answers.

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1. For the following molecules, find the number of unique proton signals that would be
observed in ¹H NMR. Label the equivalent protons and give the multiplicity and
integration for each. See the example for methyl ethyl ketone. Please note that singlet or
multiplicity 1 are both acceptable answers.
Example:
H3C
H3C.
H₂
H3C.
CH3
H3C C -CH₂
CH3
H3C)
A
CH₂Cl2
OH
-Br
CH3
H₂
CH3
CH3
с
H₂
B
CH3
с
2. The following set of molecules each show a singlet. The chemical shifts (ppm) are 0.232,
3.052, 5.297 and 7.256. Match the shift to each molecule below.
A: Singlet (Multiplicity 1) Integration 3
B: Quartet (Multiplicity 4) Integration 2
C: Triplet (Multiplicity 3) Integration 3
CHC13
CH,C1
CH4
Transcribed Image Text:1. For the following molecules, find the number of unique proton signals that would be observed in ¹H NMR. Label the equivalent protons and give the multiplicity and integration for each. See the example for methyl ethyl ketone. Please note that singlet or multiplicity 1 are both acceptable answers. Example: H3C H3C. H₂ H3C. CH3 H3C C -CH₂ CH3 H3C) A CH₂Cl2 OH -Br CH3 H₂ CH3 CH3 с H₂ B CH3 с 2. The following set of molecules each show a singlet. The chemical shifts (ppm) are 0.232, 3.052, 5.297 and 7.256. Match the shift to each molecule below. A: Singlet (Multiplicity 1) Integration 3 B: Quartet (Multiplicity 4) Integration 2 C: Triplet (Multiplicity 3) Integration 3 CHC13 CH,C1 CH4
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