How would you synthesize the following substances from benzaldehyde and reagents from the table? In general, the fewer the steps, the better the synthesis. You should not need more than four steps. Use letters from the table to list reagents in the order used (first at the left) with no commas. Example: cag a CH2=0 Reagents f 1. CH3MgBr/dry ether 2 H₂O* j 1. P(C6H5)3 2. BuLi Br₂ b O C (C6H5)3P-CH2 g Dess-Martin periodinane in CH2Cl2 h 1. NaBH4 2. H3O+ 1. PBг3 d m NH + acid i 1. BH3/THF NaNH2/NH3 2. H2O2/NaOH CrO3/H₂O* n Mg/ dry ether a) Previous Next
Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
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