How many unique c's can be seen on 13C NMR and how would the peaks be assigned? Product is 4-acetylbiphenyl and solvent is CDCl3

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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How many unique c's can be seen on 13C NMR and how would the peaks be assigned? Product is 4-acetylbiphenyl and solvent is CDCl3

CH3
Transcribed Image Text:CH3
200
190
1³C[¹H] NMR of product in CDCI3
180
170
160
150
140
130
129.5 129.0
120
wwwwwww
128.5 128.0 127.5 127.0 126.
f1 (ppm)
110
f1 (ppm)
100
90
80
solvent
CĐC13
70
60
50
40
30
20
Transcribed Image Text:200 190 1³C[¹H] NMR of product in CDCI3 180 170 160 150 140 130 129.5 129.0 120 wwwwwww 128.5 128.0 127.5 127.0 126. f1 (ppm) 110 f1 (ppm) 100 90 80 solvent CĐC13 70 60 50 40 30 20
Expert Solution
Step 1

Each set of chemically equivalent carbons in a compound produces a separate signal in its 13C -NMR spectrum.

Saturated hydrocarbons have among the lower chemical shifts value that is (0–50 ppm); electronegative atom attached carbons like alcohols, alkyl halides, and amines have chemical shifts that are somewhat farther downfield (10–90 ppm), followed by the unsaturated hydrocarbons and more stable aromatic carbons (100–170 ppm) and finally back bone of organic compound functional group carbonyl carbons (150–220 ppm).

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