Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Identify each compound below from its molecular formula and its 13C NMR spectrum.
![b. CyHyBr
200
175
150
125
100
75
50
25
8 (ppm)
frequemey
c. CHy0
212
200
180
160
120
100
20
8 (ppm)
frequency](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9dcb6adc-1e8e-4cf5-9506-7ed65a8dcdf5%2Fb462d15f-0522-44bc-95ad-172a393a27f2%2Fnb5xn18.jpeg&w=3840&q=75)
Transcribed Image Text:b. CyHyBr
200
175
150
125
100
75
50
25
8 (ppm)
frequemey
c. CHy0
212
200
180
160
120
100
20
8 (ppm)
frequency
Expert Solution
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Step 1
The following rules should be followed to deduce the structure of unknown compound from the 13-C NMR data.
1) Check the number of signals in the spectrum which gives information regarding number of non-equivalent carbons in the molecule.
2) Identify the easily predictable signals in the spectrum, from which derive the possible fragments.
3) Subtract the chemical formula of all the derived fragments from the given molecular formula to know the remaining fragment.
4) At last, assemble all the fragments to get the structure of molecule which satisfies the given data.
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