How could the following pairs of isomeric compounds be differentiated by mass spectrometry (draw the appropriate mechanism of cation formation, rearrangement): CH3 CH3 Ň CH3 H3C N H CH3 N,N-dimethylpropanamide - N-methylbutanamide (1:1)

How could the following pairs of isomeric compounds be differentiated by mass spectrometry (draw the appropriate mechanism of cation formation, rearrangement): CH3 CH3 Ň CH3 H3C N H CH3 N,N-dimethylpropanamide - N-methylbutanamide (1:1)

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter26: Biomolecules: Amino Acids, Peptides, And Proteins

Section26.SE: Something Extra

Problem 53AP

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How could the following pairs of isomeric compounds be differentiated by mass
spectrometry (draw the appropriate mechanism of cation formation,
rearrangement):
CH3
CH3
CH3
H3C
N
H
CH3
N,N-dimethylpropanamide - N-methylbutanamide (1:1)

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