Heat transfer to and from a reaction flask is often a critical factor in controlling reaction rate. The heat transferred (q) depends on a heat transfer coefficient (h) for the flask material, the temperature difference (∆T) across the flask wall, and the commonly “wetted” area (A) of the flask and bath, q = hA∆T. When an exothermic reaction is run at a given T, there is a bath temperature at which the reaction can no longer be controlled, and the reaction “runs away” suddenly. A similar problem is often seen when a reaction is “scaled up” from, say, a half-filled small flask to a half-filled large flask. Explain these behaviors.

Elements Of Electromagnetics
7th Edition
ISBN:9780190698614
Author:Sadiku, Matthew N. O.
Publisher:Sadiku, Matthew N. O.
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Heat transfer to and from a reaction flask is often a
critical factor in controlling reaction rate. The heat transferred (q)
depends on a heat transfer coefficient (h) for the flask material,
the temperature difference (∆T) across the flask wall, and the
commonly “wetted” area (A) of the flask and bath, q = hA∆T.
When an exothermic reaction is run at a given T, there is a bath
temperature at which the reaction can no longer be controlled, and
the reaction “runs away” suddenly. A similar problem is often seen
when a reaction is “scaled up” from, say, a half-filled small flask to
a half-filled large flask. Explain these behaviors.

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