HCl reacts with propene (CH;CHCH;) in the gas phase according to the overall reaction HCI + CH,CHCH, — СН,СНCICH, The experimental rate expression is rate = k[HCI]°[CH,CHCH2] Which, if any, of the following mechanisms are consistent with the observed rate expression? (a) HCl + HCl=H+HCl, Н+ CH:CHCH2 — СH:CHCH3 (fast equilibrium) (slow) HCI + CH,CHCH, — СH,СНCICH; + HC (fast) (fast equilibrium) (b) HCl + HCl 2H¿Cl2 HCI + CH;CHCH2 2 CH;CHCICH; (fast equilibrium) CH;CHCICH; + H2C12 → CH;CHCICH3 + 2 HCI (slow) (c) HCI + CH,CHСH; — Н + СH;CHCICH, (fast equilibrium) (fast equilibrium) H2CI + CH;CHCICH, → HCI + CH;CHCICH; H + HCI2H,CI (slow)
HCl reacts with propene (CH;CHCH;) in the gas phase according to the overall reaction HCI + CH,CHCH, — СН,СНCICH, The experimental rate expression is rate = k[HCI]°[CH,CHCH2] Which, if any, of the following mechanisms are consistent with the observed rate expression? (a) HCl + HCl=H+HCl, Н+ CH:CHCH2 — СH:CHCH3 (fast equilibrium) (slow) HCI + CH,CHCH, — СH,СНCICH; + HC (fast) (fast equilibrium) (b) HCl + HCl 2H¿Cl2 HCI + CH;CHCH2 2 CH;CHCICH; (fast equilibrium) CH;CHCICH; + H2C12 → CH;CHCICH3 + 2 HCI (slow) (c) HCI + CH,CHСH; — Н + СH;CHCICH, (fast equilibrium) (fast equilibrium) H2CI + CH;CHCICH, → HCI + CH;CHCICH; H + HCI2H,CI (slow)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![HCl reacts with propene (CH;CHCH;) in the gas phase
according to the overall reaction
HCI + CH,CHCH, — СН,СНCICH,
The experimental rate expression is
rate = k[HCI]°[CH,CHCH2]
Which, if any, of the following mechanisms are consistent
with the observed rate expression?
(a) HCl + HCl=H+HCl,
Н+ CH:CHCH2 — СH:CHCH3
(fast equilibrium)
(slow)
HCI + CH,CHCH, — СH,СНCICH; + HC
(fast)
(fast equilibrium)
(b) HCl + HCl 2H¿Cl2
HCI + CH;CHCH2 2 CH;CHCICH;
(fast equilibrium)
CH;CHCICH; + H2C12 → CH;CHCICH3 + 2 HCI
(slow)
(c) HCI + CH,CHСH; — Н + СH;CHCICH,
(fast equilibrium)
(fast equilibrium)
H2CI + CH;CHCICH, → HCI + CH;CHCICH;
H + HCI2H,CI
(slow)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fab28a626-43f4-4e94-b1b0-223aa2862c4f%2F86c2b4cb-1e51-4e1d-96fc-df64adc610f7%2Fhenwtxr.png&w=3840&q=75)
Transcribed Image Text:HCl reacts with propene (CH;CHCH;) in the gas phase
according to the overall reaction
HCI + CH,CHCH, — СН,СНCICH,
The experimental rate expression is
rate = k[HCI]°[CH,CHCH2]
Which, if any, of the following mechanisms are consistent
with the observed rate expression?
(a) HCl + HCl=H+HCl,
Н+ CH:CHCH2 — СH:CHCH3
(fast equilibrium)
(slow)
HCI + CH,CHCH, — СH,СНCICH; + HC
(fast)
(fast equilibrium)
(b) HCl + HCl 2H¿Cl2
HCI + CH;CHCH2 2 CH;CHCICH;
(fast equilibrium)
CH;CHCICH; + H2C12 → CH;CHCICH3 + 2 HCI
(slow)
(c) HCI + CH,CHСH; — Н + СH;CHCICH,
(fast equilibrium)
(fast equilibrium)
H2CI + CH;CHCICH, → HCI + CH;CHCICH;
H + HCI2H,CI
(slow)
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 5 steps with 13 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY