Consider the following reaction for chlorine reacting with chloroform,Cl2 (g) + CHCIl3 (g)HС (g) + СCla (g)a) based on the initial rate data provided (in the table below), determine the ratelaw for this reaction.b) The following is a proposed mechanism for this reaction.Cl2 (g) = 2 CI (g)CI (g) + CHCI: (g) → HCI (g) + CCl: (g) (slow)CCl: (g) + CI (g) > Сle (g)(fast equilibrium)(fast)Is this an acceptable mechanism based on the rate law you determined in part a?answer should be Yes/No to "is this an acceptable mechanism")Initial Rate [CI,] [CHCI3]0.00253 | 0.2 0.3A) Yes0.007590.20.9B) No0.005060.80.3

(a) The given reaction is, Cl2(g) + CHCl3(g) → HCl(g) + CCl4(g) Initial rate data is,

Consider the following reaction for chlorine reacting with chloroform, Cl: (g) + CHCI; (g) → HCI (g) + CCIla (g) a) based on the initial rate data provided (in the table below), determine the rate law for this reaction. b) The following is a proposed mechanism for this reaction. Cl: (g) = 2 CI (g) CI (g) + CHCI (g) → HCI (g) + CCI (g) (slow) CCI: (g) + CI (g) → CCI. (g) (fast equilibrium) (fast) Is this an acceptable mechanism based on the rate law you determined in part a? answer should be Yes/No to "is this an acceptable mechanism") Initial Rate [Cl] [CHCI3]| 0.00253 0.2 0.3 A) Yes 0.00759 0.2 0.9 B) No 0.00506 0.8 0.3

Consider the following reaction for chlorine reacting with chloroform, Cl: (g) + CHCI; (g) → HCI (g) + CCIla (g) a) based on the initial rate data provided (in the table below), determine the rate law for this reaction. b) The following is a proposed mechanism for this reaction. Cl: (g) = 2 CI (g) CI (g) + CHCI (g) → HCI (g) + CCI (g) (slow) CCI: (g) + CI (g) → CCI. (g) (fast equilibrium) (fast) Is this an acceptable mechanism based on the rate law you determined in part a? answer should be Yes/No to "is this an acceptable mechanism") Initial Rate [Cl] [CHCI3]| 0.00253 0.2 0.3 A) Yes 0.00759 0.2 0.9 B) No 0.00506 0.8 0.3

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Consider the following reaction for chlorine reacting with chloroform,
Cl2 (g) + CHCIl3 (g)
HС (g) + СCla (g)
a) based on the initial rate data provided (in the table below), determine the rate
law for this reaction.
b) The following is a proposed mechanism for this reaction.
Cl2 (g) = 2 CI (g)
CI (g) + CHCI: (g) → HCI (g) + CCl: (g) (slow)
CCl: (g) + CI (g) > Сle (g)
(fast equilibrium)
(fast)
Is this an acceptable mechanism based on the rate law you determined in part a?
answer should be Yes/No to "is this an acceptable mechanism")
Initial Rate [CI,] [CHCI3]
0.00253 | 0.2 0.3
A) Yes
0.00759
0.2
0.9
B) No
0.00506
0.8
0.3

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