The actual structure of SF4 places the lone pair in only one of two possible sites. To discuss thestability of the observed structures, we need only consider bond angles <120°. Repulsion effectsat angles 2120° are generally ignored. Consider the structure below.axiale) If the LP goes into the equatorial position labelled A, there will be[2/3/4]x 90° angles between the LP and each BP.OBequatorialf) If the LP goes into the axial position labelled B, there will be[2/314]x 90° angles between the LP and each BP.equatorialaxialg) Considering your answers given in e) and f) above.The most stable arrangement of EGs in SF4 places the LP in the [ axial / equatorial ]position.h) Looking at the molecular groups for AXs and AX6 in the table on page 3, it can bedetermined that the order of magnitude for EG repulsion is:i.LP/BP = BP/BP > LP/LPii.BP/BP >> LP/BP > LP/LPLP/BP > BP/BP >> LP/LPLP/LP >>> LP/BP > BP/BPLP/LP = LP/BP = BP/BPii.iv.V.

h) Looking at the molecular groups for AXs and AX6 in the table on page 3, it can be determined that the order of magnitude for EG repulsion is: LP/BP = BP/BP > LP/LP BP/BP >> LP/BP > LP/LP LP/BP > BP/BP >> LP/LP i. %3D ii. iii. LP/LP >>> LP/BP > BP/BP LP/LP = LP/BP = BP/BP iv. V.

h) Looking at the molecular groups for AXs and AX6 in the table on page 3, it can be determined that the order of magnitude for EG repulsion is: LP/BP = BP/BP > LP/LP BP/BP >> LP/BP > LP/LP LP/BP > BP/BP >> LP/LP i. %3D ii. iii. LP/LP >>> LP/BP > BP/BP LP/LP = LP/BP = BP/BP iv. V.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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