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]>90% e.e. racemic 1) TSOH (cat.), CH,Cl2 then workup но mostly one diastereomer <5:1 diastereomer mix product after these transformations 2) a) NaNH,, THF, -20 °C b) OHC-CH,CH, c) workup >90% e.e. racemic mostly one diastereomer 3) NaH, MegSi-CI, then workup 6:1 diastereomer mix product after these transformations

]>90% e.e. racemic 1) TSOH (cat.), CH,Cl2 then workup но mostly one diastereomer <5:1 diastereomer mix product after these transformations 2) a) NaNH,, THF, -20 °C b) OHC-CH,CH, c) workup >90% e.e. racemic mostly one diastereomer 3) NaH, MegSi-CI, then workup 6:1 diastereomer mix product after these transformations

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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]>90% e.e. TSOH (cat.), CH,Cl2 then workup racemic но mostly one diastereomer ]5:1 diastereomer mix product after these transformations >90% e.e. 2) a) NANH2, THF, -20 °C b) OHC-CH,CH3 c) workup ]racemic mostly one diastereomer 3) NaH, MegSi-CI, then workup ] 5:1 diastereomer mix product after these transformations
Transcribed Image Text:]>90% e.e. TSOH (cat.), CH,Cl2 then workup racemic но mostly one diastereomer ]5:1 diastereomer mix product after these transformations >90% e.e. 2) a) NANH2, THF, -20 °C b) OHC-CH,CH3 c) workup ]racemic mostly one diastereomer 3) NaH, MegSi-CI, then workup ] 5:1 diastereomer mix product after these transformations
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