When a new chirality center is created, isomers can result. For the reaction below, draw all of the major organic products using hashed and wedged bonds to show stereochemistry
When a new chirality center is created, isomers can result. For the reaction below, draw all of the major organic products using hashed and wedged bonds to show stereochemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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When a new chirality center is created, isomers can result. For the reaction below, draw all of the major organic products using hashed and wedged bonds to show stereochemistry
![When a new chirality center is created, isomers can result. For the reaction below, draw all of the major organic products using hashed and wedged bonds to show stereochemistry.
\[ \text{Reaction:} \]
\[ \text{Reactant with double bond and chiral centers} \]
- \(\text{H}_3\text{C} \) and \(\text{H} \) groups indicated with wedged/hashed bonds at the chiral centers.
- 0.05 eq. OsO\(_4\)
- 1.2 eq. oxidant, e.g., NMO or t-BuOOH
### Instructions:
- Use the wedge/hash bond tools to indicate stereochemistry where it exists.
- If the reaction produces a racemic mixture, draw both stereoisomers.
- Show stereochemistry in a meso compound.
- Separate multiple products using the '+' sign from the drop-down menu.
### Tools:
- Includes various drawing and structure editing tools, such as bond, ring, and charge tools.
This educational diagram illustrates the importance of understanding stereochemistry and the generation of isomers in organic reactions, particularly when new chiral centers are formed.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc8ea2db0-7475-4a7d-bef3-e03d95cf57eb%2F8e4fffb1-d2d3-4665-929c-a6de2d4438e0%2Fgkihf9s_processed.jpeg&w=3840&q=75)
Transcribed Image Text:When a new chirality center is created, isomers can result. For the reaction below, draw all of the major organic products using hashed and wedged bonds to show stereochemistry.
\[ \text{Reaction:} \]
\[ \text{Reactant with double bond and chiral centers} \]
- \(\text{H}_3\text{C} \) and \(\text{H} \) groups indicated with wedged/hashed bonds at the chiral centers.
- 0.05 eq. OsO\(_4\)
- 1.2 eq. oxidant, e.g., NMO or t-BuOOH
### Instructions:
- Use the wedge/hash bond tools to indicate stereochemistry where it exists.
- If the reaction produces a racemic mixture, draw both stereoisomers.
- Show stereochemistry in a meso compound.
- Separate multiple products using the '+' sign from the drop-down menu.
### Tools:
- Includes various drawing and structure editing tools, such as bond, ring, and charge tools.
This educational diagram illustrates the importance of understanding stereochemistry and the generation of isomers in organic reactions, particularly when new chiral centers are formed.
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