Given the following reduction half-reactions: Fe*(ag) + e → Fe2* (aq) Eed = +0.77 V S202- (ag) + 4 H*(aq) + 2 e → 2 H2SO3(aq) Ered = +0.60 V N20(8) + 2H*(aq) + 2 e¯ → N2(8) + H;0(I) Eed –1.77 V voj(aq) + 2H*(aq) + e- → VO2+ + H,0(I) Ered = +1.00V (a) Write balanced chemical equations for the oxidation of Fe2"(aq) by S20? (aq), by N20(aq), and by VO* (aq). (b) Calculate AG" for each reaction at 298 K. (c) Calculate the equilibrium constant K for each reaction at 298 K.

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Given the following reduction half-reactions:
Fe*(ag) + e →
Fe2* (aq) Eed = +0.77 V
S202- (ag) + 4 H*(aq) + 2 e → 2 H2SO3(aq) Ered = +0.60 V
N20(8) + 2H*(aq) + 2 e¯ → N2(8) + H;0(I) Eed
–1.77 V
voj(aq) + 2H*(aq) + e- → VO2+ + H,0(I) Ered = +1.00V
(a) Write balanced chemical equations for the oxidation
of Fe2"(aq) by S20? (aq), by N20(aq), and by VO* (aq).
(b) Calculate AG" for each reaction at 298 K. (c) Calculate
the equilibrium constant K for each reaction at 298 K.
Transcribed Image Text:Given the following reduction half-reactions: Fe*(ag) + e → Fe2* (aq) Eed = +0.77 V S202- (ag) + 4 H*(aq) + 2 e → 2 H2SO3(aq) Ered = +0.60 V N20(8) + 2H*(aq) + 2 e¯ → N2(8) + H;0(I) Eed –1.77 V voj(aq) + 2H*(aq) + e- → VO2+ + H,0(I) Ered = +1.00V (a) Write balanced chemical equations for the oxidation of Fe2"(aq) by S20? (aq), by N20(aq), and by VO* (aq). (b) Calculate AG" for each reaction at 298 K. (c) Calculate the equilibrium constant K for each reaction at 298 K.
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