Given that the plausible mechanism for a reaction: 2NO (g) +O2 (g) → 2NO2 (g), was proposed as follows: Step 1: NO (g) + NO (g) N,O2 (g) (fast) Step 2: N,02 (g) +0, (g) 2NO, (g) (slow) (i) Sketch the energy profile diagram for the plausible mechanism above. Label the diagram with all the important features including reactants, products, activated complex/intermediates, activation energy and the enthalpy of the reaction. (ii) Determine the rate law for the above reaction.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Given that the plausible mechanism for a reaction: 2NO (g) + O2 (g) → 2NO2 (g), was proposed
as follows:
Step 1: NO (g) + NO (g)
N202 (g) (fast)
Step 2: N,02 (g) +0, (g)
2NO, (g) (slow)
Sketch the energy profile diagram for the plausible mechanism above. Label the
diagram with all the important features including reactants, products, activated
complex/intermediates, activation energy and the enthalpy of the reaction.
(i)
(ii)
Determine the rate law for the above reaction.
Transcribed Image Text:Given that the plausible mechanism for a reaction: 2NO (g) + O2 (g) → 2NO2 (g), was proposed as follows: Step 1: NO (g) + NO (g) N202 (g) (fast) Step 2: N,02 (g) +0, (g) 2NO, (g) (slow) Sketch the energy profile diagram for the plausible mechanism above. Label the diagram with all the important features including reactants, products, activated complex/intermediates, activation energy and the enthalpy of the reaction. (i) (ii) Determine the rate law for the above reaction.
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