Suppose the formation of nitryl fluoride proceeds by the following mechanism: elementary reaction rate constant NO₂ (g)+F₂ (g) → NO₂F (g) +F (g) 1 k₁ F (g) +NO₂ (g) NO₂F (g) k₂ Suppose also k₁ <

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Chapter1: Chemical Foundations
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Suppose the formation of nitryl fluoride proceeds by the following mechanism:
step
elementary reaction
1 NO₂ (g) +F₂ (g) → NO₂F (g)+F (g)
2
F (g) + NO₂ (g) → NO₂F (g)
Suppose also k₁ << k₂. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
0
rate = &
rate constant
k₁
k₂
Transcribed Image Text:Suppose the formation of nitryl fluoride proceeds by the following mechanism: step elementary reaction 1 NO₂ (g) +F₂ (g) → NO₂F (g)+F (g) 2 F (g) + NO₂ (g) → NO₂F (g) Suppose also k₁ << k₂. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. 0 rate = & rate constant k₁ k₂
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