G 5% Carbocation Rearrangements 7) Draw the 5 MOST LIKELY carbocation rearrangements of the following intermediate. Bonus: Put an X next to the least likely structure and briefly explain why. alk of
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- *5% Carbocation Rearrangements 7) Draw the 5 MOST LIKELY carbocation rearrangements of the following intermediate. Bonus: Put an X next to the least likely structure and briefly explain why. H okWhich of the given reactions would form meso product? H₂O, H2SO4 III m CH3 CH₂ONa CH3OH || H₂O, H2SO4 CH3 1. LiAlH4, THF 2. H₂O CH3 IV3. Draw ALL THE POSSBILE PRODUCTS AND THE MECHANISMS WITH ALL RESONANCE STRUCTURES. Explain using the resonance structures why the major product(s) are formed over the minor product(s). H₂SO4, HONO CH
- 2. Draw the carbocation rearrangements for each of the following carbocations. yeThe cis isomer of 1-bromo-4-tert-butylcyclohexane undergoes E2 elimination about 1,000 times faster than the trans isomer. Explain why the cis isomer reacts faster. Hint: It is not because of steric hindrance. Br + NaOH Fast (H3C),C (H3C);C Br + NaOH Slow (H3C);C' (H3C);C2. Draw the carbocation intermediates (if any exist) and the products for each reaction. Include any intermediates and products arising from carbocation rearrangements. Be sure to include stereochemistry!!! 1. ВНз 2. Н2О2, NaOн H2SO4 H20 Br2 HO. H2SO4 HOʻ
- Determine the mechanism of nucleophilic substitution of each reaction and draw the products, including stereochemistr CH₂CH3 CI Br + CN d. + CH3COOH a. acetone + -OCH3 e. DMF f. b. C. ||||| a ||||| Br H Br CH2CH2CH3 + CH3OH DMSO H CH3 CI Br + OCH₂CH3 + CH3CH₂OHWhat are the possible constitutional isomers and rank by SN2 reaction.The reaction shown can give two different mono-alkylation products depending on the conditions. Draw the kinetic and thermodynamic products of the reaction. 1. base Kinetic + Thermodynamic Products 2. CH3CH₂Br (1 equiv.) Draw the kinetic product. Draw the thermodynamic product. Select Draw Rings More Erase Select Draw Rings More Erase / ||| ||| C H O / || III C H O