G 5% Carbocation Rearrangements 7) Draw the 5 MOST LIKELY carbocation rearrangements of the following intermediate. Bonus: Put an X next to the least likely structure and briefly explain why. alk of
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- The cis isomer of 1-bromo-4-tert-butylcyclohexane undergoes E2 elimination about 1,000 times faster than the trans isomer. Explain why the cis isomer reacts faster. Hint: It is not because of steric hindrance. Br + NaOH Fast (H3C),C (H3C);C Br + NaOH Slow (H3C);C' (H3C);C2. Draw the carbocation intermediates (if any exist) and the products for each reaction. Include any intermediates and products arising from carbocation rearrangements. Be sure to include stereochemistry!!! 1. ВНз 2. Н2О2, NaOн H2SO4 H20 Br2 HO. H2SO4 HOʻThe reaction shown can give two different mono-alkylation products depending on the conditions. Draw the kinetic and thermodynamic products of the reaction. 1. base Kinetic + Thermodynamic Products 2. CH3CH₂Br (1 equiv.) Draw the kinetic product. Draw the thermodynamic product. Select Draw Rings More Erase Select Draw Rings More Erase / ||| ||| C H O / || III C H O
- Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.In the E2 reaction of 2-bromopentane with sodium tert-butoxide, 1-pentene is favored over 2- pentene. It is based on O the size of base used. O the Zaisev's rule. O the strength of the base used. O the Hoffman product. O the stability of alkeneCurved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. H Br2 (1 equiv) H- Select to Draw Starting Alkene Draw Major Product I I H2O 四: ⑦.. Q Draw Major Charged Intermediate I
- In the first box, draw the tetrahedral intermediate involved in this reaction.In the second box, draw the product of the reaction.Include all lone pairs of electrons and nonzero formal charges. Do not add curved arrows.1. Draw the mechanism for the following reaction. Include all intermediates, formal charges, and arrows. ol CH3CH₂NH2 H*, -H₂OQuestion 5 1). Draw all resonance structures for the carbocation intermediate formed by para attack; circle the resonance structure that is particularly unstable. N- N Cl₂ AICI 3 H 2). Draw all resonance structures for the carbocation intermediate formed by ortho attack; circle the extra resonance structure that is particularly stable. H a Aer ANSAS C HNO3 H₂SO4
- 2. Draw the product(s) of the following reaction and a mechanism. Include all resonance structures of the intermediate. AICI3Draw curved arrows for the following reaction step. Arrow-pushing Instructions CH3 CH3 .. H-0-H .. H3C-C-Ci: H3C-C+ :ci: ČH3 CH3Draw the missing produts for the reaction shown below. Be sure to include stereochemistry where appropriate.