7. For an octahedral complex (ds configuration) three bands are observed at energies of 11000,14667, and 22800 cm-1. Shown below is the Tanabe-Sugano diagram for the ds case.a) Find the racah parameter (B) and the value of A, ?b) Draw a possible UV-vis spectrum and assigned the all spin-allowed electronic transitions usingOrgel diagram80Eg7060 -IT1s5040 -30203pE10³F10203040A/BE/B

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For an octahedral complex (d$ configuration) three bands are observed at energies of 11000, 14667, and 22800 cm-1. Shown below is the Tanabe-Sugano diagram for the d8 case. ) Find the racah parameter (B) and the value of A, ?

For an octahedral complex (d$ configuration) three bands are observed at energies of 11000, 14667, and 22800 cm-1. Shown below is the Tanabe-Sugano diagram for the d8 case. ) Find the racah parameter (B) and the value of A, ?

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter21: Structure And Bonding In Solids

Section: Chapter Questions

Problem 64CP

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Question

7. For an octahedral complex (ds configuration) three bands are observed at energies of 11000,
14667, and 22800 cm-1. Shown below is the Tanabe-Sugano diagram for the ds case.
a) Find the racah parameter (B) and the value of A, ?
b) Draw a possible UV-vis spectrum and assigned the all spin-allowed electronic transitions using
Orgel diagram
80
Eg
70
60 -
IT
1s
50
40 -
30
20
3p
E
10
³F
10
20
30
40
A/B
E/B

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