Consider the UV-Vis spectrum of a metal complex given below: a) b) c) d) e) Absorbance 1.2 1 0.8 0.6 0.4 0.2 0 -0.2 400 450 500 550 Wavelength (nm) 600 650 700 Determine the approximate value of max from the spectrum. Briefly discuss the type of electron transitions for a coordination complex which can be observed in a UV spectrum. Determine whether the spectrum above is for [Co(H2O)6]³+ or [Co(CN)6]³-. Explain your answer. Explain why the absorbance bands observed in UV-Vis spectra are broad and not well- defined (sharp). Draw a general schematic of the layout of a typical UV-Vis spectrophotometer.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter24: Introduction To Spectrochemical Methods
Section: Chapter Questions
Problem 24.21QAP
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Consider the UV-Vis spectrum of a metal complex given below:
b)
d)
Absorbance
e)
1.2
1
0.8
0.6
0.4
0.2
0
-0.2
400
450
500
550
Wavelength (nm)
.!.
600
a) Determine the approximate value of max from the spectrum.
Briefly discuss the type of electron transitions for a coordination complex which can be
observed in a UV spectrum.
650
700
Determine whether the spectrum above is for [Co(H2O)6]³+ or [Co(CN)6]³-. Explain your
answer.
Explain why the absorbance bands observed in UV-Vis spectra are broad and not well-
defined (sharp).
Draw a general schematic of the layout of a typical UV-Vis spectrophotometer.
Transcribed Image Text:Consider the UV-Vis spectrum of a metal complex given below: b) d) Absorbance e) 1.2 1 0.8 0.6 0.4 0.2 0 -0.2 400 450 500 550 Wavelength (nm) .!. 600 a) Determine the approximate value of max from the spectrum. Briefly discuss the type of electron transitions for a coordination complex which can be observed in a UV spectrum. 650 700 Determine whether the spectrum above is for [Co(H2O)6]³+ or [Co(CN)6]³-. Explain your answer. Explain why the absorbance bands observed in UV-Vis spectra are broad and not well- defined (sharp). Draw a general schematic of the layout of a typical UV-Vis spectrophotometer.
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