Fill in the missing information for the reaction shown: NO3¯+ H2 --> NO2¯ + H2O deltaGo' = kJ Under standard physiological conditions, this reaction is gonic
Fill in the missing information for the reaction shown: NO3¯+ H2 --> NO2¯ + H2O deltaGo' = kJ Under standard physiological conditions, this reaction is gonic
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Table 20.1
Standard Reduction Potentlals for Several Blological Reduction Half-Reactions
8,' (V)
Reduction Half-Reaction
o, + 2 H* + 2 H,O
Fe* +e Fe+
Photosystem P700
NO,- + 2 H* +2r NO, + H,O
Cytochrome f(Fe*) +e cytochrome f(Fe+)
Cytochrome a (Fe*") +e cytochrome a(Fe")
Cytochrome a(Fe**) +- cytochrome a(Fe")
Rieske Fe-S(Fe") +e Rieske Fe-S(Fe")
Cytochrome e(Fe**) +e cytochrome e (Fe*)
Cytochrome 4(Fe) +r cytochrome g(Fe*)
UQH- + H +r UQH, (UQ = coenzyme Q
UQ + 2 H* + 2e- UQH,
Cytochrome b,(Fe) +e - cytochrome b(Fe)
Fumarate + 2 H* + 2 e succinate
UQ + H* + UQH -
Cytochrome b, (Fe") +e
[FAD] + 2 H* +2r [FADH,]
Cytochrome be(Fe*) +e- cytochrome & (Fe*)
Oxaloacetate + 2 H* +2e - malate
Pyruvate + 2 H* +2e lactate
Acetaldehyde + 2 H* +2e - ethanol
FMN + 2 H* + 2r- FMNH,
FAD + 2 H* + 2e FADH,
Glutathione (oxidized) + 2 H +2r 2 glutathione (reduced)
Lipoic acid + 2 H* + 2e dihydrolipoic acid
1,3-Bisphosphoglycerate + 2 H* + 2e-
glyceraldehyde-3-phosphate + P.
NAD + 2 H* + 2r- NADH + H*
NADP + 2 H* + 2e NADPH + H*
Lipoyl dehycdrogenase [FAD] + 2 H* + 2e-
lipoyl dehydrogenase [FADH,]
0.816
0.771
0.430
0.421
0.365
0.350
0.290
0.280
0.254
0.220
0.190
0.060
0.050
0.031
0.030
cytochrome b, (Fe)
0.020
0.003-0.091*
-0.100
-0.166
-0.185
-0.197
-0.219
-0.219
-0.230
-0.290
-0.290
-0.320
-0.320
-0.340
a-Ketoglutarate + CO, + 2 H+ + 2e isocitrate
2 H* +2e H,
Ferredoxin (spinach) (Fe") +e ferredoxin (spinach) (Fe)
Succinate + CO, + 2 H + 2e a-ketoglutarate + H,O
-0.380
-0.421
-0.430
-0.670](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Feaa0a3cf-7191-460e-853f-8c7461e94293%2F12dd3127-b0dd-46e2-a428-ce0a2d843bbd%2Fo5i713u_processed.png&w=3840&q=75)
Transcribed Image Text:Table 20.1
Standard Reduction Potentlals for Several Blological Reduction Half-Reactions
8,' (V)
Reduction Half-Reaction
o, + 2 H* + 2 H,O
Fe* +e Fe+
Photosystem P700
NO,- + 2 H* +2r NO, + H,O
Cytochrome f(Fe*) +e cytochrome f(Fe+)
Cytochrome a (Fe*") +e cytochrome a(Fe")
Cytochrome a(Fe**) +- cytochrome a(Fe")
Rieske Fe-S(Fe") +e Rieske Fe-S(Fe")
Cytochrome e(Fe**) +e cytochrome e (Fe*)
Cytochrome 4(Fe) +r cytochrome g(Fe*)
UQH- + H +r UQH, (UQ = coenzyme Q
UQ + 2 H* + 2e- UQH,
Cytochrome b,(Fe) +e - cytochrome b(Fe)
Fumarate + 2 H* + 2 e succinate
UQ + H* + UQH -
Cytochrome b, (Fe") +e
[FAD] + 2 H* +2r [FADH,]
Cytochrome be(Fe*) +e- cytochrome & (Fe*)
Oxaloacetate + 2 H* +2e - malate
Pyruvate + 2 H* +2e lactate
Acetaldehyde + 2 H* +2e - ethanol
FMN + 2 H* + 2r- FMNH,
FAD + 2 H* + 2e FADH,
Glutathione (oxidized) + 2 H +2r 2 glutathione (reduced)
Lipoic acid + 2 H* + 2e dihydrolipoic acid
1,3-Bisphosphoglycerate + 2 H* + 2e-
glyceraldehyde-3-phosphate + P.
NAD + 2 H* + 2r- NADH + H*
NADP + 2 H* + 2e NADPH + H*
Lipoyl dehycdrogenase [FAD] + 2 H* + 2e-
lipoyl dehydrogenase [FADH,]
0.816
0.771
0.430
0.421
0.365
0.350
0.290
0.280
0.254
0.220
0.190
0.060
0.050
0.031
0.030
cytochrome b, (Fe)
0.020
0.003-0.091*
-0.100
-0.166
-0.185
-0.197
-0.219
-0.219
-0.230
-0.290
-0.290
-0.320
-0.320
-0.340
a-Ketoglutarate + CO, + 2 H+ + 2e isocitrate
2 H* +2e H,
Ferredoxin (spinach) (Fe") +e ferredoxin (spinach) (Fe)
Succinate + CO, + 2 H + 2e a-ketoglutarate + H,O
-0.380
-0.421
-0.430
-0.670

Transcribed Image Text:QUESTION 38
Fill in the missing information for the reaction shown:
NO3 + H2 --> NO2¯+H2O
deltaGo' =
kJ
Under standard physiological conditions, this reaction is
gonic
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