Ethers containing the 1,1-dimethylethyl (tert-butyl) group are readily cleaved with dilute, strong acid. Draw curved arrows to suggest a plausible mechanism for this process. H₂C-CH₂ CH3 CH-O-C- -CH3 H₂C-CH₂ CH3 H₂C-CH₂ H3C Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally make a mistake, remove the last change by using the undo button on the lower left or revert the drawing palette to the original state by selecting the More menu, then select Reset Drawing. H₂C Step 1: Draw a curved arrow. H₂C CF3CO₂H, H₂O CH₂ CH₂ H₂C-CH₂ CH₂ H₂C CH-OH H + H HC с Ofe Ote HC 0 с c c - c H₂ H₂ + H₂C H3C C=CH₂ Step 2: Draw a curved arrow. CH₂ CH₂ CH₂
Ethers containing the 1,1-dimethylethyl (tert-butyl) group are readily cleaved with dilute, strong acid. Draw curved arrows to suggest a plausible mechanism for this process. H₂C-CH₂ CH3 CH-O-C- -CH3 H₂C-CH₂ CH3 H₂C-CH₂ H3C Do not delete any pre-drawn bonds, charges, or lone pairs. If you accidentally make a mistake, remove the last change by using the undo button on the lower left or revert the drawing palette to the original state by selecting the More menu, then select Reset Drawing. H₂C Step 1: Draw a curved arrow. H₂C CF3CO₂H, H₂O CH₂ CH₂ H₂C-CH₂ CH₂ H₂C CH-OH H + H HC с Ofe Ote HC 0 с c c - c H₂ H₂ + H₂C H3C C=CH₂ Step 2: Draw a curved arrow. CH₂ CH₂ CH₂
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter26: Aldol And Claisen Reactions
Section: Chapter Questions
Problem 26E
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