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ethane 2C,H6(g) +702(g) 4C0,(g) + 6H,O(1) Explain why it is unlikely that this equation also rep- resents the elementary step for the reaction. 13.54 Specify which of the following species cannot be isolated in a reaction: activated complex, product, Me intermediate. Me Problems 13.55 The rate law for the reaction 13.6 Cata 2NO(g) + Cl,(g) 2NOCI(g) Review Qu is given by rate = k[NO][Cl,]. (a) What is the order of the reaction? (b) A mechanism involving the following steps has been proposed for the reaction: 13.59 Ho %3D 13.60 Wh 13.61 A c ro tion NO(g) + Cl2(g) NOCI (g) NOCI,(g) + NO(g) 2NOCI(g) -> tem 13.62 Dist hete If this mechanism is correct, what does it imply about the relative rates of these two steps? indu 13.56 For the reaction X, + Y+Z XY+ XZ it is talys found that doubling the concentration of X, doubles the reaction rate, tripling the concentration of Y tri- ples the rate, and doubling the concentration of Z has no effect. (a) What is the rate law for this reac- tion? (b) Why is it that the change in the concentra- tion of Z has no effect on the rate? (c) Suggest a mechanism for the reaction that is consistent with 13.63 Are gene 13.64 The quite this f Problems the rate law. 13.65 The mech and th 13.57 The rate law for the decomposition of ozone to mo- lecular oxygen diate 20,(g) -30,(g) and B is tow

ethane 2C,H6(g) +702(g) 4C0,(g) + 6H,O(1) Explain why it is unlikely that this equation also rep- resents the elementary step for the reaction. 13.54 Specify which of the following species cannot be isolated in a reaction: activated complex, product, Me intermediate. Me Problems 13.55 The rate law for the reaction 13.6 Cata 2NO(g) + Cl,(g) 2NOCI(g) Review Qu is given by rate = k[NO][Cl,]. (a) What is the order of the reaction? (b) A mechanism involving the following steps has been proposed for the reaction: 13.59 Ho %3D 13.60 Wh 13.61 A c ro tion NO(g) + Cl2(g) NOCI (g) NOCI,(g) + NO(g) 2NOCI(g) -> tem 13.62 Dist hete If this mechanism is correct, what does it imply about the relative rates of these two steps? indu 13.56 For the reaction X, + Y+Z XY+ XZ it is talys found that doubling the concentration of X, doubles the reaction rate, tripling the concentration of Y tri- ples the rate, and doubling the concentration of Z has no effect. (a) What is the rate law for this reac- tion? (b) Why is it that the change in the concentra- tion of Z has no effect on the rate? (c) Suggest a mechanism for the reaction that is consistent with 13.63 Are gene 13.64 The quite this f Problems the rate law. 13.65 The mech and th 13.57 The rate law for the decomposition of ozone to mo- lecular oxygen diate 20,(g) -30,(g) and B is tow

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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ethane 2C,H6(g) +702(g) 4C0,(g) + 6H,O(1) Explain why it is unlikely that this equation also rep- resents the elementary step for the reaction. 13.54 Specify which of the following species cannot be isolated in a reaction: activated complex, product, Me intermediate. Me Problems 13.55 The rate law for the reaction 13.6 Cata 2NO(g) + Cl,(g) 2NOCI(g) Review Qu is given by rate = k[NO][Cl,]. (a) What is the order of the reaction? (b) A mechanism involving the following steps has been proposed for the reaction: 13.59 Ho %3D 13.60 Wh 13.61 A c ro tion NO(g) + Cl2(g) NOCI (g) NOCI,(g) + NO(g) 2NOCI(g) -> tem 13.62 Dist hete If this mechanism is correct, what does it imply about the relative rates of these two steps? indu 13.56 For the reaction X, + Y+Z XY+ XZ it is talys found that doubling the concentration of X, doubles the reaction rate, tripling the concentration of Y tri- ples the rate, and doubling the concentration of Z has no effect. (a) What is the rate law for this reac- tion? (b) Why is it that the change in the concentra- tion of Z has no effect on the rate? (c) Suggest a mechanism for the reaction that is consistent with 13.63 Are gene 13.64 The quite this f Problems the rate law. 13.65 The mech and th 13.57 The rate law for the decomposition of ozone to mo- lecular oxygen diate 20,(g) -30,(g) and B is tow
Transcribed Image Text:ethane 2C,H6(g) +702(g) 4C0,(g) + 6H,O(1) Explain why it is unlikely that this equation also rep- resents the elementary step for the reaction. 13.54 Specify which of the following species cannot be isolated in a reaction: activated complex, product, Me intermediate. Me Problems 13.55 The rate law for the reaction 13.6 Cata 2NO(g) + Cl,(g) 2NOCI(g) Review Qu is given by rate = k[NO][Cl,]. (a) What is the order of the reaction? (b) A mechanism involving the following steps has been proposed for the reaction: 13.59 Ho %3D 13.60 Wh 13.61 A c ro tion NO(g) + Cl2(g) NOCI (g) NOCI,(g) + NO(g) 2NOCI(g) -> tem 13.62 Dist hete If this mechanism is correct, what does it imply about the relative rates of these two steps? indu 13.56 For the reaction X, + Y+Z XY+ XZ it is talys found that doubling the concentration of X, doubles the reaction rate, tripling the concentration of Y tri- ples the rate, and doubling the concentration of Z has no effect. (a) What is the rate law for this reac- tion? (b) Why is it that the change in the concentra- tion of Z has no effect on the rate? (c) Suggest a mechanism for the reaction that is consistent with 13.63 Are gene 13.64 The quite this f Problems the rate law. 13.65 The mech and th 13.57 The rate law for the decomposition of ozone to mo- lecular oxygen diate 20,(g) -30,(g) and B is tow
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