Energy and the First Law of Thermodynamics: We have discussed in the previous discussion the connection of energy with the first law of thermodynamics. From this point, we are interested to calculate the change in internal energy of the system and determine whether the process is endothermic or exothermic: (a) A balloon is cooled by removing 0.655 kJ of heat. It shrinks on cooling, and the atmosphere does 382 J of work on the balloon. (b) A 100.0-g bar of gold is heated from 25 °C to 50 °C during which it absorbs 322 J of heat. Assume the volume of the gold bar remains constant. (c) The surroundings do 1.44 kJ of work compressing gas in a perfectly insulated cylinder.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. Energy and the First Law of Thermodynamics: We have discussed in the previous discussion the
connection of energy with the first law of thermodynamics. From this point, we are interested to calculate
the change in internal energy of the system and determine whether the process is endothermic or
exothermic: (a) A balloon is cooled by removing 0.655 kJ of heat. It shrinks on cooling, and the
atmosphere does 382 J of work on the balloon. (b) A 100.0-g bar of gold is heated from 25 °C to 50 °C
during which it absorbs 322 J of heat. Assume the volume of the gold bar remains constant. (c) The
surroundings do 1.44 kJ of work compressing gas in a perfectly insulated cylinder.
Transcribed Image Text:1. Energy and the First Law of Thermodynamics: We have discussed in the previous discussion the connection of energy with the first law of thermodynamics. From this point, we are interested to calculate the change in internal energy of the system and determine whether the process is endothermic or exothermic: (a) A balloon is cooled by removing 0.655 kJ of heat. It shrinks on cooling, and the atmosphere does 382 J of work on the balloon. (b) A 100.0-g bar of gold is heated from 25 °C to 50 °C during which it absorbs 322 J of heat. Assume the volume of the gold bar remains constant. (c) The surroundings do 1.44 kJ of work compressing gas in a perfectly insulated cylinder.
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