Effect of the ratio of the conjugate base to the weak acid. CASE 1. From the Henderson-Hasselbach equation, calculate the ratio of dihydrogen phosphate (H2PO4-) and monohydrogen phosphate (HPO4-2) components required to produce buffer solution with     1. pH 6.2     2. pH 7.2     3. pH 8.2 CASE 2. From the Henderson-Hasselbach equation, calculate the ratio of acetic acid and acetate required to produce buffer solution with:     1. pH 3.7     2. pH 4.7     3. pH 5.7

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Chapter15: Acid-base Equilibria
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Problem 2ALQ: A friend asks the following: Consider a buffered solution made up of the weak acid HA and its salt...
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H2PO4- + H2O ======== HPO4^-2 + H3O+

2. Effect of the ratio of the conjugate base to the weak acid.

CASE 1. From the Henderson-Hasselbach equation, calculate the ratio of dihydrogen phosphate (H2PO4-) and monohydrogen phosphate (HPO4-2) components required to produce buffer solution with
    1. pH 6.2
    2. pH 7.2
    3. pH 8.2

CASE 2. From the Henderson-Hasselbach equation, calculate the ratio of acetic acid and acetate required to produce buffer solution with:

    1. pH 3.7
    2. pH 4.7
    3. pH 5.7
Using the stock solution provided to you, make 25 mL of each of the buffer solutions assigned to you. Measure and record the pH of each of the buffer solutions. Add 2 mL of 0.1 M NaOH to each of the 25 mL buffer solutions. Record the pH of each buffer solution after addition of alkali. Account for the magnitude of pH shift in each with reference to the direction of pH shift.

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