Draw the curly arrow mechanism (including the products formed) for this hydrolysis. Make sure that all the arrows start from the correct electron pair, i.e., do not copy the mechanism given in the lecture PP-presentations. Draw the corresponding active site (with substrate) for an inverting a- glycosidase.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 30CTQ
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2. Below is given a general presentation of the active site of an inverting B-glycosyl
hydrolase (glycosidase) including the substrate.
:0: O
Ö-R
:0:
H
i)
Draw the curly arrow mechanism (including the products formed) for this
hydrolysis. Make sure that all the arrows start from the correct electron pair,
i.e., do not copy the mechanism given in the lecture PP-presentations.
ii)
Draw the corresponding active site (with substrate) for an inverting a-
glycosidase.
Transcribed Image Text:2. Below is given a general presentation of the active site of an inverting B-glycosyl hydrolase (glycosidase) including the substrate. :0: O Ö-R :0: H i) Draw the curly arrow mechanism (including the products formed) for this hydrolysis. Make sure that all the arrows start from the correct electron pair, i.e., do not copy the mechanism given in the lecture PP-presentations. ii) Draw the corresponding active site (with substrate) for an inverting a- glycosidase.
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