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Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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**Title: Estimating the Enthalpy of Reaction for Sulfur Tetrafluoride Monoxide Formation**

**Introduction:**
Understanding chemical reactions involves estimating the energy changes that occur. This can be done by analyzing bond energies. Here, we will estimate the enthalpy change (\(\Delta H_{\text{rxn}}\)) for the formation of sulfur tetrafluoride monoxide (\(\text{SOF}_4\)).

**Chemical Structure:**
The Lewis structure of sulfur tetrafluoride monoxide (\(\text{SOF}_4\)) shows sulfur (S) centrally connected to an oxygen (O) atom and four fluorine (F) atoms, each with pairs of valence electrons indicating lone pairs around the F and O atoms.

**Bond Energies:**
Use the following bond energies (kJ/mol) to calculate the enthalpy change:

| Bond  | Energy (kJ/mol) |
|-------|-----------------|
| S–F   | 310             |
| S–O   | 265             |
| S=O   | 523             |
| O–O   | 142             |
| O=O   | 498             |
| O–F   | 180             |

**Calculation:**
Estimate \(\Delta H_{\text{rxn}}\) using the bond energies provided to determine the overall energy change for breaking and forming bonds in the reaction.

**Enthalpy Change Calculation Box:**
\[ \Delta H_{\text{rxn}} = \text{(Fill in with calculation result)} \, \text{kJ/mol} \]

**Conclusion:**
Accurate knowledge of bond energies allows for the estimation of reaction energetics, crucial for predicting reaction behavior and stability.
Transcribed Image Text:**Title: Estimating the Enthalpy of Reaction for Sulfur Tetrafluoride Monoxide Formation** **Introduction:** Understanding chemical reactions involves estimating the energy changes that occur. This can be done by analyzing bond energies. Here, we will estimate the enthalpy change (\(\Delta H_{\text{rxn}}\)) for the formation of sulfur tetrafluoride monoxide (\(\text{SOF}_4\)). **Chemical Structure:** The Lewis structure of sulfur tetrafluoride monoxide (\(\text{SOF}_4\)) shows sulfur (S) centrally connected to an oxygen (O) atom and four fluorine (F) atoms, each with pairs of valence electrons indicating lone pairs around the F and O atoms. **Bond Energies:** Use the following bond energies (kJ/mol) to calculate the enthalpy change: | Bond | Energy (kJ/mol) | |-------|-----------------| | S–F | 310 | | S–O | 265 | | S=O | 523 | | O–O | 142 | | O=O | 498 | | O–F | 180 | **Calculation:** Estimate \(\Delta H_{\text{rxn}}\) using the bond energies provided to determine the overall energy change for breaking and forming bonds in the reaction. **Enthalpy Change Calculation Box:** \[ \Delta H_{\text{rxn}} = \text{(Fill in with calculation result)} \, \text{kJ/mol} \] **Conclusion:** Accurate knowledge of bond energies allows for the estimation of reaction energetics, crucial for predicting reaction behavior and stability.
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