Decide whether each of the molecules in the table below is stable, in the exact form in which it is drawn, at pH = 11. If you decide at least one molecule is not stable, then redraw one of the unstable molecules in its stable form below the table. (If more than one molecule is unstable, you can pick any of them to redraw.) HO 40 OH Ostable O unstable .OH HO stable O unstable X Ostable Ounstable HO OH Ostable O unstable

Decide whether each of the molecules in the table below is stable, in the exact form in which it is drawn, at pH = 11. If you decide at least one molecule is not stable, then redraw one of the unstable molecules in its stable form below the table. (If more than one molecule is unstable, you can pick any of them to redraw.) HO 40 OH Ostable O unstable .OH HO stable O unstable X Ostable Ounstable HO OH Ostable O unstable

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter8: Bonding: General Concepts

Section: Chapter Questions

Problem 136AE: Write Lewis structures for CO32, HCO3, and H2CO3. When acid is added to an aqueous solution...

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Write Lewis structures for CO32, HCO3, and H2CO3. When acid is added to an aqueous solution containing carbonate or bicarbonate ions, carbon dioxide gas is formed. We generally say that carbonic acid (H2C03) is unstable. Use bond energies to estimate E for the reaction (in the gas phase) H2CO3CO2+H2O Specify a possible cause for the instability of carbonic acid.
Compound ∆Hf (kJ/mole) ∆S (J/mole K) C2H4 52.4 219.3 C2H6 –84.68 229.2 SiO2 –910.7 41.5 HF –273.3 173.8 SiF4 –1615.0 282.8 NH3 –45.9 192.9 O2 1.88 2.43 NO 91.3 210.8 H2O(g) –241.8 188.8 For the following reactions, using the provided ∆H and ∆S data, determine whether each one would be spontaneous or nonspontaneous at 25°C. C2H4(g) + H2(g) --------à C2H6(g) SiO2 + 4 HF(g) -------------> SiF4 (g) + 2 H2O(g) 4 NH3(g) + 5 O (g) ---------> 4 NO(g) + 6 H2O(g)
Compound ∆Hf (kJ/mole) ∆S (J/mole K) C2H4 52.4 219.3 C2H6 –84.68 229.2 SiO2 –910.7 41.5 HF –273.3 173.8 SiF4 –1615.0 282.8 NH3 –45.9 192.9 O2 1.88 2.43 NO 91.3 210.8 H2O(g) –241.8 188.8 4 NH3 + 5 O2 -> 4 NO + 6 H2O
The breaking of the O-O bond in peroxydisulfuryl difluoride (FO,SOOSO,F) gives FO,SO: (FO2SO)2 2 2 FO2SO The compound on the left of this equation is a colorless liquid that boils at 67.1°C. Its vapor, when heated to about 100°C, turns brown as the product of the reaction forms. Suppose that, in a sample of the vapor, the intensity of the brown color doubles between 100°C and 110°C and that the total pressure increases only by the 2.7% predicted for an ideal gas. Estimate AH° for the preceding reaction.
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2. Use the table below to estimate AH for the reaction NO + O3 → NO2 + O2. Does this reaction consume or produce heat? Single Bond Energies (kJ/mol of bonds) н сN oS F C Br I Н 436 C 413 346 N 391 305 163 O 463 358 201 146 S 347 272 226 - F 565 485 283 190 284 155 Cl 432 339 192 218 255 253 242 Br 366 285 201 217 249 216 193 - I 299 213 201 278 208 175 151 - - Multiple Bond Energies (kJ/mol of bonds) C=C 602 C=N 615 C=O 799 C=C 835 CEN 887 C=O 1072 N=N 418 N=O 607 N=N 945 O=O 498
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Use the bond enthaplies in this table to determine triangleH for the formafion of hydrazine, N2H4, according to this equation.
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Calculate the AHn for this reaction using the given bond energies: CH4(g) + 2 H,0(g)→ 4H>(g) + CO,(g) Bond Energy (kJ/mol) 49. H-H 436 O-H 464 H-C 414 C=O 799 -357 kJ b) +170 kJ c) -170 kJ d) +357 kJ
The conversion of graphite into diamond is an endothermic reaction (AH = +3 kJ mol-1). C(graphite) → C(diamond) 1 The enthalpy change of atomisation of diamond is smaller than that of graphite. The bond energy of the C-C bonds in graphite is greater than that in diamond. 2 The enthalpy change of combustion of diamond is greater than that of graphite. 3 Which statements are correct? A 1, 2 and 3 B 1 and 2 only C 2 and 3 only D 1 only