Data Table Initial Final Change in Temperature (°C) 5.30 Reaction Mass of # solution (g) Temperature (°C) 25 Temperature (°C) 30.30 1 50 50 25 36.97 11.97 3 50 25 31.67 6.67 Processing Data 1. Calculate the heat energy released for each reaction. Show all your work.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Data Table
Initial
Change in
Temperature
(°C)
Reaction
Mass of
Final
%23
solution (g)
Temperature
(°C)
Temperature
(°C)
50
25
30.30
5.30
2
50
25
36.97
11.97
3
50
25
31.67
6.67
Processing Data
1. Calculate the heat energy released for each reaction. Show all your work.
Reaction 1:
Reaction 2:
Reaction 3:
2. Write net ionic equations for Reactions 1, 2 and 3. Consider the heat given off in
your reactions; include the heat evolved in kJ/mole for each reaction.
Reaction1:
Reaction 2:
Reaction 3:
3. The energy in Reaction 1 represents the energy of solution for one mole of NaOH
(s). Look at the net ionic equations for Reactions 2 and 3, and make a similar
statement concerning the significance of AH for reactions 2 and 3.
4. Apply Hess's Law using the sum of reaction 1 and reaction 3 to find the
experimental value of AH for reactions 2. Show your work below.
5. Calculate the percent error between the value of AH for reaction 2 and the sum of
AH for reaction 1 plus AH for reaction 3. (Assume AH for reaction 2 to be the
accepted value). Show your work. Account for any similarity or difference.
6. Suppose you had used 4.00 grams of NaOH(s) in Reaction 1. What would have
been the number of Joules released in the reaction? What effect would this have
on the value of AH for reaction 1?
Transcribed Image Text:Data Table Initial Change in Temperature (°C) Reaction Mass of Final %23 solution (g) Temperature (°C) Temperature (°C) 50 25 30.30 5.30 2 50 25 36.97 11.97 3 50 25 31.67 6.67 Processing Data 1. Calculate the heat energy released for each reaction. Show all your work. Reaction 1: Reaction 2: Reaction 3: 2. Write net ionic equations for Reactions 1, 2 and 3. Consider the heat given off in your reactions; include the heat evolved in kJ/mole for each reaction. Reaction1: Reaction 2: Reaction 3: 3. The energy in Reaction 1 represents the energy of solution for one mole of NaOH (s). Look at the net ionic equations for Reactions 2 and 3, and make a similar statement concerning the significance of AH for reactions 2 and 3. 4. Apply Hess's Law using the sum of reaction 1 and reaction 3 to find the experimental value of AH for reactions 2. Show your work below. 5. Calculate the percent error between the value of AH for reaction 2 and the sum of AH for reaction 1 plus AH for reaction 3. (Assume AH for reaction 2 to be the accepted value). Show your work. Account for any similarity or difference. 6. Suppose you had used 4.00 grams of NaOH(s) in Reaction 1. What would have been the number of Joules released in the reaction? What effect would this have on the value of AH for reaction 1?
INTRODUCTION:
In this experiment, you will determine and compare the quantity of heat energy released
in three exothermic chemical reactions.
O Reaction 1: Solid sodium hydroxide dissolves in water to form an aqueous solution
of ions.
O Reaction 2: Solid sodium hydroxide reacts with an aqueous solution of hydrogen
chloride to form water and an aqueous solution of sodium chloride.
O Reaction 3: An aqueous solution of sodium hydroxide reacts with an aqueous
solution of hydrogen chloride to form water and an aqueous solution of sodium
chloride.
In order to accurately measure the heat released in each reaction, we will be using a
calorimeter (for this experiment a Styrofoam cup will act as the calorimeter). The change
in temperature that occurs for each reaction will be used to calculate the energy released
in kilojoules per mole of sodium hydroxide used. We can assume for our calculations that
any heat transferred to the Styrofoam and surrounding air will be negligible. We can also
assume that the specific heat of any aqueous solution is 4.18 J/g °C.
PROCEDURE:
Simulation Link: http://chemcollective.org/vlab/138
A. Reaction 1
1. In the glassware menu, take out a 50 mL graduated cylinder and a foam cup. From
the instruments menu, take out of the scale. From the chemical stockroom, move
the distilled water and solid NaOH on to the workbench.
2. Transfer 50.0 mL of water to the foam cup. To do this, drag the container of water
on the graduated cylinder. (Before you release the mouse button, the cylinder will
turn blue to indicate that it is the recipient). A transfer text-bar will activate at the
bottom of the screen. Enter "50.0" (ml) and click on pour. (You will notice that the
graduated cylinder reads 50.0 mL).
3. Weigh about 1 gram of solid sodium hydroxide pellets, NaOH(s), directly into the
foam cup and record its mass to the nearest 0.01 gram. To do this, place the foam
cup on the balance so it registers a mass, then click the "Tare" button. Drag the
NaOH bottle onto then foam cup. (When you release the mouse, the bottle will be
tipped to show that it is in pour mode). Next, type "1.00" (grams) into the transfer
bar and then click pour. Note that the balance now reads the mass of the
transferred NaOH. You may now take the cup off of the scale and remove the scale
from the workbench.
4. Click on the graduated cylinder and record its temperature.
5. Drag the graduated cylinder onto the foam cup. (When you release the mouse, the
graduated cylinder will be tipped to show that it is in pour mode.) Enter "50.0" in
the transfer bar and then click pour.
6. Record the highest temperature.
7. Remove all equipment from the laboratory bench.
B. Reaction 2
1. Take the 0.5 M HCI from the strong acids cabinet, a new foam cup, and a 50 mL
graduated cylinder from the glassware menu and place them on the workbench.
2. Transfer 50.0 mL of 0.50 M hydrochloric acid solution to the graduated cylinder in
place of the water.
3. After measuring 50.0 mL of the HCI solution into the graduated cylinder, proceed
as before with steps 3 to 6 of the procedure followed for Reaction 1.
4. Record the highest temperature.
5. Remove all equipment from the laboratory bench.
C. Reaction 3
1. Take out another graduated cylinder, a fresh foam cup, the 1.0 M HCI and 1.0 M
NaOH.
2. Measure 25.0 mL of 1.0 M hydrochloric acid solution using the graduated cylinder
and pour into the foam cup.
3. Pour an equal volume of 1.0 M sodium hydroxide solution in the clean graduated
cylinder.
4. Record the temperature of each solution to the nearest 0.1°C.
5. Pour the sodium hydroxide solution into the foam cup and record the highest
temperature obtained during the reaction.
Transcribed Image Text:INTRODUCTION: In this experiment, you will determine and compare the quantity of heat energy released in three exothermic chemical reactions. O Reaction 1: Solid sodium hydroxide dissolves in water to form an aqueous solution of ions. O Reaction 2: Solid sodium hydroxide reacts with an aqueous solution of hydrogen chloride to form water and an aqueous solution of sodium chloride. O Reaction 3: An aqueous solution of sodium hydroxide reacts with an aqueous solution of hydrogen chloride to form water and an aqueous solution of sodium chloride. In order to accurately measure the heat released in each reaction, we will be using a calorimeter (for this experiment a Styrofoam cup will act as the calorimeter). The change in temperature that occurs for each reaction will be used to calculate the energy released in kilojoules per mole of sodium hydroxide used. We can assume for our calculations that any heat transferred to the Styrofoam and surrounding air will be negligible. We can also assume that the specific heat of any aqueous solution is 4.18 J/g °C. PROCEDURE: Simulation Link: http://chemcollective.org/vlab/138 A. Reaction 1 1. In the glassware menu, take out a 50 mL graduated cylinder and a foam cup. From the instruments menu, take out of the scale. From the chemical stockroom, move the distilled water and solid NaOH on to the workbench. 2. Transfer 50.0 mL of water to the foam cup. To do this, drag the container of water on the graduated cylinder. (Before you release the mouse button, the cylinder will turn blue to indicate that it is the recipient). A transfer text-bar will activate at the bottom of the screen. Enter "50.0" (ml) and click on pour. (You will notice that the graduated cylinder reads 50.0 mL). 3. Weigh about 1 gram of solid sodium hydroxide pellets, NaOH(s), directly into the foam cup and record its mass to the nearest 0.01 gram. To do this, place the foam cup on the balance so it registers a mass, then click the "Tare" button. Drag the NaOH bottle onto then foam cup. (When you release the mouse, the bottle will be tipped to show that it is in pour mode). Next, type "1.00" (grams) into the transfer bar and then click pour. Note that the balance now reads the mass of the transferred NaOH. You may now take the cup off of the scale and remove the scale from the workbench. 4. Click on the graduated cylinder and record its temperature. 5. Drag the graduated cylinder onto the foam cup. (When you release the mouse, the graduated cylinder will be tipped to show that it is in pour mode.) Enter "50.0" in the transfer bar and then click pour. 6. Record the highest temperature. 7. Remove all equipment from the laboratory bench. B. Reaction 2 1. Take the 0.5 M HCI from the strong acids cabinet, a new foam cup, and a 50 mL graduated cylinder from the glassware menu and place them on the workbench. 2. Transfer 50.0 mL of 0.50 M hydrochloric acid solution to the graduated cylinder in place of the water. 3. After measuring 50.0 mL of the HCI solution into the graduated cylinder, proceed as before with steps 3 to 6 of the procedure followed for Reaction 1. 4. Record the highest temperature. 5. Remove all equipment from the laboratory bench. C. Reaction 3 1. Take out another graduated cylinder, a fresh foam cup, the 1.0 M HCI and 1.0 M NaOH. 2. Measure 25.0 mL of 1.0 M hydrochloric acid solution using the graduated cylinder and pour into the foam cup. 3. Pour an equal volume of 1.0 M sodium hydroxide solution in the clean graduated cylinder. 4. Record the temperature of each solution to the nearest 0.1°C. 5. Pour the sodium hydroxide solution into the foam cup and record the highest temperature obtained during the reaction.
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