Cyclic forms of D-glucose: Haworth formula The furanose and pyranose forms of D-glucose can be presented using Haworth formula. The following templates are used for this formula. Note the numbering of the carbon atoms and the anomeric carbon (this carbon defines the alpha and beta isomer). Furanose template (furan) Pyranose template (pyran) anomeric carbon anomeric carbon Compare the Fisher and Haworth formula of D-glucofuranose and D-glucopyranose. Notice that the groups attached to C-1, C-2, and C-3 on the left side of the Fisher formula are written above the plane of the furanose template. Fisher formula Haworth formula H FOH H-2FOH 0 HOH,Č 5 ОН HO-3FH 4 он H 1 H-4 H-5FOH OH 2. 3 6 CH2OH Alpha-D-glucofuranose H OH Alpha-D-glucofuranose HOH2C- он но H. HO- он H но H OH FHO- CH2OH Beta-D-glucofuranose Beta-D-glucofuranose
Cyclic forms of D-glucose: Haworth formula The furanose and pyranose forms of D-glucose can be presented using Haworth formula. The following templates are used for this formula. Note the numbering of the carbon atoms and the anomeric carbon (this carbon defines the alpha and beta isomer). Furanose template (furan) Pyranose template (pyran) anomeric carbon anomeric carbon Compare the Fisher and Haworth formula of D-glucofuranose and D-glucopyranose. Notice that the groups attached to C-1, C-2, and C-3 on the left side of the Fisher formula are written above the plane of the furanose template. Fisher formula Haworth formula H FOH H-2FOH 0 HOH,Č 5 ОН HO-3FH 4 он H 1 H-4 H-5FOH OH 2. 3 6 CH2OH Alpha-D-glucofuranose H OH Alpha-D-glucofuranose HOH2C- он но H. HO- он H но H OH FHO- CH2OH Beta-D-glucofuranose Beta-D-glucofuranose
Biochemistry
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ISBN:9781319114671
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Chapter1: Biochemistry: An Evolving Science
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