Can you explain why the answer E ? And also why not A . A states that five member ring . Isn’t it should be six member ring?

Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
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Can you explain why the answer E ? And also why not A . A states that five member ring . Isn’t it should be six member ring?
1. Regarding cyclic structures of monosaccharides and cyclitols, such as myo-inositol shown
below, the following is FALSE:
2.
HO.
OH
OH
OH
OH
OH
A. Some hexoses exist in the five-membered ring (hexofuranose) form.
B. In aqueous solutions, equilibrium exists between five- and six-membered ring structures.
C. In aqueous solutions, equilibrium exists between - and -hexopyranoses.
D. In aqueous solutions, monosaccharides exist in equilibrium between the cyclic and linear
open-chain forms.
НО
myo-inositol
E. In aqueous solutions, cyclitols, such myo-inositol, exist in equilibrium between the cyclic
and linear open-chain forms.
F. Carbocyclic analogs of monosaccharides, such as myo-inositol (see above), are much
more chemically and metabolically stable than monosaccharides.
HO
Lactulose, a -glycoside that is not hydrolyzed by amylases, is used for treatment of portal
encephalopathy. This condition is caused by an elevated level of ammonia in the brain due
to liver cirrhosis. What is the mechanism of lactulose action?
НО
OH
EX
OH
OH
OH
OH
Transcribed Image Text:1. Regarding cyclic structures of monosaccharides and cyclitols, such as myo-inositol shown below, the following is FALSE: 2. HO. OH OH OH OH OH A. Some hexoses exist in the five-membered ring (hexofuranose) form. B. In aqueous solutions, equilibrium exists between five- and six-membered ring structures. C. In aqueous solutions, equilibrium exists between - and -hexopyranoses. D. In aqueous solutions, monosaccharides exist in equilibrium between the cyclic and linear open-chain forms. НО myo-inositol E. In aqueous solutions, cyclitols, such myo-inositol, exist in equilibrium between the cyclic and linear open-chain forms. F. Carbocyclic analogs of monosaccharides, such as myo-inositol (see above), are much more chemically and metabolically stable than monosaccharides. HO Lactulose, a -glycoside that is not hydrolyzed by amylases, is used for treatment of portal encephalopathy. This condition is caused by an elevated level of ammonia in the brain due to liver cirrhosis. What is the mechanism of lactulose action? НО OH EX OH OH OH OH
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